Introduction of versatile and recyclable network poly (ionic liquid)s as an efficient solvent with desired properties for application in C-C cross-coupling reactions
Abstract:Synthesis of high viscosity, ecofriendly, and low melting point poly(ionic liquid)s (LMP-PIL) with network structure has been introduced by the reaction of TAIm[I] ionic liquid monomer with disodium salts of various open-chain carboxylic acids as well as sulfonic acids via a polycondensation on counter ions (PC-CI). Changes in methylene group numbers of carboxylate, as well as sulfonate, provide a broad spectrum of properties in terms of viscosity, density, and solubility for the resulting PILs. The physical p… Show more
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