Introduction

The First Platinum Formyl, a Member of a Series of Hexanuclear Clusters Exhibiting a Rare Structure We thank the Ministero dell'Università e della Ricerca Scientifica e Tecnologica (MURST), Programmi di Interesse Nazionale, 2000–2001, for financial support.

“…In particular, the triplet for the formyl group at δ =18.9 ( 3 J (H,P)=14 Hz) in the 1 H NMR spectrum of 4 splits as expected in 4 * (br dt, 1 J (C,H)=152 Hz) for coupling with the adjacent 13 C nucleus (Figure 2 a, b). The same coupling is exhibited by a doublet at δ =244.6 for the formyl C atom in the proton‐coupled 13 C NMR spectrum of 4 * (Figure 2 c, d) 6a. Furthermore, a ν C=O band at 1604 cm −1 in the IR spectrum of 4 shifts to 1574 cm −1 in the spectrum of 4 * 6a…”

Metal etching with organic based plasmas. II. CO∕NH3 plasmas

“…23 Nitrogen containing ligands include N,Ndimethylethylenediamine ͑dmen͒, 24 N,Ndiethylethylenediamine ͑deen͒, 24 and acetylacetonime ͑acim͒. Metal formates are well-known, 26 but not used in MOCVD because the ligands are too stongly bound to readily dissociate upon adsorbtion, a feature that is a detriment as an MOCVD precursor, but a strength as a possible etch product. The two most common bonding motifs are shown at the bottom of the figure.…”

Magnetic metal etching with organic based plasmas. I. CO∕H2 plasmas

“…29 Both of these molecules are readily capable of assuming a bidentate ligand geometry that is similar to that of acac and thd. Metal formates are well-known, 30 but are not used in MOCVD because the ligands are too strongly bound to readily dissociate upon adsorption, a feature that is a detriment as an MOCVD precursor, but a strength for etch product. 31 The ethenediol in the plasma is closely related to dmen and denn and also readily assumes a bidentate ligand geometry, supporting its possible role in etching.…”