-We present the comparison of results from the generation and the measurement of direct currents in the pA range, performed with traceable state-of-the-art methods at highest accuracy. The currents were generated with the capacitor charging method, and measured with the first prototype of a novel picoammeter developed at PTB. The results confirm the agreement between both methods and the linearity of the new picoammeter at an uncertainty level of few µA/A. Also, they shed light on the ac-dc difference of capacitors, crucial for current generation with the capacitor charging method.