“…These studies show that complex 1 is a strong two‐electron reducing agent and two separate one‐electron oxidation steps, with potentials at +0.93 V and +1.20 V, have been detected . In this way, complex 1 has been used as a two‐electron reducing agent in reactions with elemental chalcogens (E = S, Se, Te) and these reactions have provided organotin(II) chalcogenides {LSn} 2 E . Analogous organotin(II) oxide {[C 6 H 3 ‐2,6‐(Me 2 NCH 2 ) 2 ]Sn} 2 O is, however, still missing, and there are only a few well‐characterized stannylene oxides , .…”