The Léon Domain in the NW part of the French Massif Armoricain is a stack of synmetamorphic nappes displaced from south to north in ductile conditions. From bottom to top, an orthogneissic basement is overthrusted successively by (1) a Lower Nappe of gneiss including mafic eclogites, (2) an Intermediate Nappe of biotite-garnet-staurolite micaschists with mafic blocks, and (3) an upper nappe made up of Neoproterozoic phyllites covered by unmetamorphosed Paleozoic sedimentary series. This microstructural study documents a polyphase evolution with firstly a top-to-the-N shearing, secondly followed by upright folding of the stack of nappes coeval with migmatization, and lastly, a dextral wrenching along the North Armorican Shear Zone associated with emplacement of synkinematic plutons. New UTh/Pb chemical dating of monazites from biotite-garnet-staurolite micaschists, migmatites, and granitoids argue for 340-335 Ma, 335-327 Ma, and about 320 Ma ages for synthrusting metamorphism, anatexis, and wrenching, respectively. A metagabbro from Le Conquet yields a zircon LA-ICP-MS age of 478 ± 4 Ma, which corresponds to magma emplacement time. The Léon Domain is interpreted as a microcontinent separated from Armorica by the Le Conquet-Penzé suture to the south and east, and from Laurussia by the Rheic suture to the north. A possible correlation with the Mid-German Crystalline Rise of Central Europe is discussed.