Interrupted thermal desorption of TiH2

Borchers, C.; Khomenko, T. I.; Леонов, А. В.; Morozova, O. S.

doi:10.1016/j.tca.2009.04.011

Cited by 39 publications

(20 citation statements)

References 30 publications

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“…The first step proceeds in the temperature range 378-457 • C and most likely corresponds to a transformation from a dihydride ␦-Ti 0.8 V 0.2 H 2−x into a monohydride ␤-Ti 0.8 V 0.2 H x . The second hydrogen evolution peak at above 500 • C indicates hydrogen desorption from ␤-Ti 0.8 V 0.2 H x to form ␤-Ti 0.8 V 0.2 , and is similar to the process in the Ti-H system [14]. From these TDS spectra, it can be inferred that rapid solidification results in a thermal destabilization of the hydride.…”

Section: Resultsmentioning

confidence: 58%

Hydrogenation and microstructural study of melt-spun Ti0.8V0.2

Suwarno

Solberg

Yartys

et al. 2011

Journal of Alloys and Compounds

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Section: Resultsmentioning

confidence: 58%

Hydrogenation and microstructural study of melt-spun Ti0.8V0.2

Suwarno

Solberg

Yartys

et al. 2011

Journal of Alloys and Compounds

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“…Interrupted TDS, which means a step-by-step heating in thermal desorption regime interrupted by fast sample cooling, is especially useful to test intermediate phase composition and has been applied to study the decomposition kinetics of TiH 2 by Borchers et al [16].…”

Section: Introductionmentioning

confidence: 99%

Decomposition kinetics study of zirconium hydride by interrupted thermal desorption spectroscopy

Liang

Tang

et al. 2015

Journal of Alloys and Compounds

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“…been observed by Yang [30] as well as Borchers [31] for desorption from titanium hydride. In those works, three TDS peaks were observed in the transition from the hydride to Ti metal and were attributed to the εTiH2 (743 K), δTiH2-x (817K) and γTIH (920 K) phases.…”

Section: However Similar Relationships Between Activation Energy Andmentioning

confidence: 83%

A thermal desorption spectroscopy study of hydrogen trapping in polycrystalline α-uranium

Lillard

Forsyth

2015

Journal of Nuclear Materials

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The kinetics of hydrogen desorption from polycrystalline α-uranium (α-U) was examined using thermal desorption spectroscopy (TDS). The goal was to identify the major trap sites for hydrogen and their associated trap energies. In α-U six TDS adsorption peaks were observed at temperatures of 521K, 556K, 607K, 681K, 793K and 905K. In addition, the desorption was determined to be second order based on peak shape. The position of the first three peaks was consistent with desorption from UH3. To identify the trap site corresponding to the high temperature peaks the data were compared to a plastically deformed sample and a high purity single crystal sample. The plastically deformed sample allowed the identification of trapping at dislocations while the single crystal sample allow for the identification of high angle boundaries and impurities. With respect to the desorption energy associated with each peak, values between 12.9 and 26.5 kJ/mole were measured.

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Interrupted thermal desorption of TiH2

Cited by 39 publications

References 30 publications

Hydrogenation and microstructural study of melt-spun Ti0.8V0.2

Hydrogenation and microstructural study of melt-spun Ti0.8V0.2

Decomposition kinetics study of zirconium hydride by interrupted thermal desorption spectroscopy

A thermal desorption spectroscopy study of hydrogen trapping in polycrystalline α-uranium

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