<p><strong>Abstract.</strong> The analysis of the aerosol optical properties derived at fine temporal and spatial scales were performed based on measurements obtained during heat wave event in vicinity of a cold weather front in Warsaw on August 9<sup>th</sup>&ndash;11<sup>th</sup>, 2015. The signals collected by the PollyXT-UW lidar allowed for the calculation of 23 sets of so-called 3<i>&beta;</i>&thinsp;+&thinsp;2<i>&alpha;</i>&thinsp;+&thinsp;2<i>&delta;</i>&thinsp;+&thinsp;wv profiles averaged by 30-minutes periods during 2 nights. The total number of 11 different aerosol types and aerosol mixtures were identified with reference to properties within 116 sub-layers in the profiles and were characterized by the mean values. The statistical sample of various optical properties being in agreement for consecutive profiles allowed to assess the spatio-temporal extent of aerosol/mixture types. The mean lidar ratio values of 53&ndash;73&thinsp;sr (355&thinsp;nm) and 31&ndash;45&thinsp;sr (532&thinsp;nm) in the layers dominated by the anthropogenic pollution were found. For the layers dominated by the biomass burning aerosol (fresh, moderately fresh, moderately aged) mean lidar ratio was of 69&ndash;114&thinsp;sr (355&thinsp;nm) and 57&ndash;85&thinsp;sr (532&thinsp;nm). The colour ratio of lidar ratio (532&thinsp;/&thinsp;355) higher than 1, characteristic for aged biomass burning aerosol, was found only in one scattered layer, accompanying with low value of extinction related Ångström exponent of 0.60&thinsp;&plusmn;&thinsp;0.32 and low particle depolarization ratio. The maximum of the particle depolarization ratio of 4.8&ndash;5.0&thinsp;% at 532&thinsp;nm were observed in a layer likely contaminated with pollen and in a layer dominated by fresh biomass burning aerosol. This study provides an excellent data set for exploration of separation algorithms, aerosol typing algorithms and microphysical inversion.</p>