Abstract:Member of the ISEThe diffusion layer is a critical factor affecting the temporal response of electrochemical devices. In this article, we have investigated the effect of the relaxation of the diffusion layer during the potentiodynamic sensing of ferrocenemethanol (FcMeOH) in microchannels and compared these results to amperometry. First, the effect of the relaxation of the diffusion layer is described, both theoretically and experimentally. Then, chronoamperometric and voltammetric measurements were conside… Show more
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