The higher the unit parameters, the more sensitive water-wall tubes are to the impurity ions in the feed water, especially when the feed water contains aggressive ions such as Clβ, SO4
2-, etc., which often cause severe corrosion to equipment. A great deal of research has been carried out to understand the characteristics of power plant boiler water wall tubes corroded by Clβ/SO4
2-, which is essential to keep industrial boilers running and power stations safe.In this paper, the author firstly elaborates on the furnace water treatment condition and the source of Clβ/SO4
2- in power plant furnace water; then, the development of water-wall tubes of the power plant corrosion study in Clβ/SO4
2- solution is summarized and discussed.