Internal Standardization in Dispersion Systems: an Efficient Application to Determine Mg in Crude Vegetable Oils by FS-FAAS

Roveda, Liriana M.; Raposo, Jorge Luiz

doi:10.1007/s12161-019-01439-1

Cited by 2 publications

(1 citation statement)

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“…Atomic absorption spectrometry (AAS) has also been used for steel and iron analysis, such as alloyed element analysis of a bulk steel sample digested with an appropriate acid mixture, 1) impurity analysis of pure iron treated by selective precipitation, 2) inclusion analysis of stainless steel prepared with electrolytic extraction, 3) and trace analysis of pure iron based on a direct atomization technique. 4) An internal standard method is effectively applied to accurate and precise AAS measurements; however, sequential measurements [5][6][7] of an analyte and an internal standard element have been insufficient to improve the precision further. On the other hand, a continuum-light-source system can be applied for the precise AAS measurement based on the internal standard method.…”

Section: Introductionmentioning

confidence: 99%

Multicomponent Internal Standard Methods for Determination of Vanadium, Chromium, Nickel, and Copper in Tool Steel Samples in Continuum-light-source Flame Atomic Absorption Spectrometry

Nakayama

Wagatsuma

2021

ISIJ Int.

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This paper suggests an improved method for the sample preparation to quantify vanadium, chromium, nickel and copper in tool steel and high-speed steel by using flame atomic absorption spectrometry. The suggested method prepared two specimen solutions containing different internal standard elements: one included nickel for the quantifications of vanadium or copper and cobalt for the quantification of chromium and another included cobalt and phosphoric acid for the quantification of nickel, after the sample was digested with an acid mixture of hydrofluoric acid, nitric acid and phosphoric acid by using a microwave oven. A multi-wavelength high-resolution spectrometer system was employed to be simultaneously measured absorption lines for several pairs of an analyte and an internal standard element, such as vanadium and nickel, chromium and cobalt, nickel and iron, cobalt and phosphorus oxide, and copper and nickel. The internal standards contributed to more accurate and precise quantification of vanadium, chromium, nickel, and copper in tool steel and high-speed steel samples.

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