The variation in thermal conductivity of polymer nanocomposite with different particle sizes and volume fractions have been investigated. Particle reinforced nano-composites with two different particle sizes and the volume ratio of each size ranging from 0 to 50 % is considered. The test is conducted using a unidirectional/linear heat transfer device that has six thermocouples to monitor the temperature flow through and across the cross section of the specimen. In addition, based on Lewis-Nielson and modified effective medium approximation, a three phase analytical model is proposed to determine the thermal conductivity of different nanocomposites. It is observed that the thermal conductivity linearly increases as the volume fraction of the particles increases. On the other hand, though the particle size has an effect on the thermal conductivity of the nanocomposites, the effect is minimal compared with the volume fraction. The analytical model has been applied to different batches of specimens, and the results from the experiment and analytical model are compared.Keywords Nanocomposite • Thermal conductivity • Kapitaz resistance • Interface layer • Surface functionalizing
IntroductionPolymers are playing a crucial role in modern material technology; they can be applied in a wide variety of applications from the electronics industry, chemical, power generation, and automotive up to aerospace industries [1-3]. There have been great efforts to improve the physical, chemical and mechanical properties of polymers by inclusion of different fillers. Carbon nanotubes, Graphenes, Glass fibers, Ceramic nanoparticles and Aluminum nanoparticles are some of the fillers used as reinforcement in nano-composites [4]. Even though nanoparticle reinforced polymer composites have proven to have many advantages, their analysis is more complicated relative to the plain polymer due to the non-uniform distribution of reinforcement and variation in properties from matrix to filler.The thermal conductivity of nano-composites plays a vital role in the overall system performance, especially in the electronic, chemical and power generation industries where these materials are used either as a thermal conductor or insulator [3]. Studies have indicated that effective thermal conductivity of nanocomposites is influenced by the thermal property of the constituents, K matrix and K filler , thickness of the interface layer (t i ), uniformity of filler distribution, filler geometry/aspect ratio and filler volume fraction [1,[4][5][6][7][8]. Out of the listed parameters, the thickness of the interface layer (t i ) is difficult to manage. To date, there have been great efforts in surface modifications techniques that are hoped to reduce or eliminate the interface layer thickness.On the other hand, functionalizing the surface of nano fillers has improved the dispersion of fillers and the interface layer between the filler and the matrix. The main focus of this paper is to investigate the effect of particle size and functionalization on the t...