“…In a very recent study, Gresil and co-workers have studies the instability of the crack propagation for vitrimer/CFRP composites. 72 The authors observed that laminates within the vitrimer matrix acquired a higher load than pure epoxy CFRP to propagate the crack, especially when interface adhesion between vitrimer matrix and the carbon fiber is strong. While considering the energy at crack propagation, fracture toughness for fibers/vitrimer was increased by ∼63%, with respect to epoxy/CF, confirming that apart from toughness of the matrix, interface and the interphase between matrix and the fibre play a very important role on fracture toughness.…”
The article covers the outstanding features of fiber-reinforced vitrimer composites, including their reprocessing, recycling and self-healing properties.
“…In a very recent study, Gresil and co-workers have studies the instability of the crack propagation for vitrimer/CFRP composites. 72 The authors observed that laminates within the vitrimer matrix acquired a higher load than pure epoxy CFRP to propagate the crack, especially when interface adhesion between vitrimer matrix and the carbon fiber is strong. While considering the energy at crack propagation, fracture toughness for fibers/vitrimer was increased by ∼63%, with respect to epoxy/CF, confirming that apart from toughness of the matrix, interface and the interphase between matrix and the fibre play a very important role on fracture toughness.…”
The article covers the outstanding features of fiber-reinforced vitrimer composites, including their reprocessing, recycling and self-healing properties.
“…Furthermore, SEM micrographs of fracture surfaces after double cantilever beam test showed matrix residues onto the carbon fibres indicating a satisfying interfacial adhesion. 56 Considering the societal invectives towards bio-based resins, the use and development of such matrices in combination with vitrimers also attracted considerable attention. 57 Based on renewable resources, Wang et al prepared a CFRP composite comprised of a Schiff base epoxy matrix with a high T g of 172°C and good mechanical properties.…”
“…Furthermore, SEM micrographs of fracture surfaces after double cantilever beam test showed matrix residues on carbon fibres indicating a satisfying interfacial adhesion. 56…”
Section: Reinforcements In Vitrimer Matrix Compositesmentioning
Thermoset dominate the composites industry owing to their outstanding stiffness to weight ratio and fatigue resistance. Nevertheless, the possibilities of recycling these materials are limited due to the irreversible chemical...
“…[1,2] The curing agents are of great importance to the properties of the cured epoxy resins. Common curing agents include amines, [3][4][5] acid anhydrides, [6][7][8][9][10] polyphenols, [11][12][13] polythiols, [14][15][16][17] and other modified curing agents. [18] Although there are currently various kinds of curing agents on the market, which can make the cured epoxy resin meet various market demands.…”
Traditional chemically cross‐linked polymer materials may cause severe environmental pollution and economic losses due to the difficulty of recycling. Vitrimers containing reversible dynamic covalent bonds are processable, recyclable, and self‐healing. In this article, a bio‐based epoxy resin curing agent is synthesized by hydrolysis using cellulose as raw material. The results show that the epoxy vitrimers with the best ratio have a lower topological transition temperature and a fast relaxation time at 140 °C. After soaking in solvent for 90 days, the gel content of the material is greater than 81%. The glass transition temperature of the sample measured by differential scanning calorimetry (DSC) is 83 °C. It also has a high initial decomposition temperature (350 °C) with good flexibility and solvent resistance, showing its good performance as a coating paint.
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