As a consequence of the detection of the fullerene series by Kroto et al.I and their consequential production in large amounts and by an easy procedure at the beginning of the nineties thanks to Kratschmer contribution,2 great interest has been concentrated on the investigations of the physical and chemical characteristics of these innovative materials. A considerable impulse to these examinations was given by the discovery of the superconductivity at high temperature which occurs when fullerenes are doped with alkali metals. 3 Fullerenes constitute a newborn and uncommon class of allotropes of carbon (the so-called third allotropic form of carbon). They and their functionalised derivatives are stimulating from both the basic and application perspectives owing to their appealing characteristics, such as superconductivity, ferromagnetism, nonlinear optical properties, charge-transfer behavior. 4 Practicable functions range from carbon composites and molecular sieves to catalysts, lubricants, optical limiters, superconducting and nanoscale devices. Anyhow, there are substantial requirements to promote processing procedures starting from fullerene and producing fullerene-derived materials that are the active constituents in thin films. In fact, in many cases, an essential requirement for the systematic investigation of the above-mentioned properties is the incorporation of fullerenes in organised 2D-arrays and 3D-networks .