Interface issues and challenges for NASICON-based solid-state sodium-metal batteries

Xiang, Le; Li, Xiutao; Xiao, Jin; Zhu, Lingyun; Zhan, Xiaowen

doi:10.1016/j.apmate.2024.100181

Advanced Powder Materials

2024

DOI: 10.1016/j.apmate.2024.100181

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Interface issues and challenges for NASICON-based solid-state sodium-metal batteries

Le Xiang,

Xiutao Li,

Jin Xiao

et al.

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2024

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Cited by 3 publications

References 117 publications

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Interfacial Modulation with Phosphorylated Covalent Organic Framework Enabling Highly Durable Sodium Metal Batteries in Carbonate‐Based Electrolytes

Hou,

Xia,

Fan

et al. 2024

Adv Funct Materials

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The practical usage of Na metal anode is severely prohibited by the instability of the natively formed solid electrolyte interface (SEI) layer and the uncontrollable Na dendrite growth, inducing short cycle life and serious safety concerns. Herein, phosphorylated covalent organic frameworks (P‐COF) is first synthesized and rationally used to construct the robust artificial interface layer for Na metal stabilization. The modified Na metal anode demonstrates high rate performance (5 mA cm−2) and ultralong cycling lifespan (1800 h) with dendrite‐free Na deposition in carbonate‐based electrolyte. And the assembled Na|Na3V2(PO4)3 (NVP) cell also reveals extraordinarily stable cycling at 5 C for 4000 cycles with a quite low decay rate of 0.002% per cycle. Moreover, the Na|NVP full cell with high areal capacity (2.0 mAh cm−2) and thin Na metal (30 µm) still demonstrates prolonged cycling over 500 cycles even under the harsh condition of a low negative‐to‐positive‐capacity (N/P) ratio of 2:3. Furthermore, the Na|NVP pouch cell with an ultrathick cathode (≈17 mg cm−2) also manifests significantly prolonged cycling performance. This work demonstrates a facile and effective strategy toward reliable Na metal batteries.

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Interfacial Modulation with Phosphorylated Covalent Organic Framework Enabling Highly Durable Sodium Metal Batteries in Carbonate‐Based Electrolytes

Hou,

Xia,

Fan

et al. 2024

Adv Funct Materials

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Engineering Interlayer Space and Composite of Square-Shaped V₂O₅ by PVP-Assisted Polyaniline Intercalation and Graphene for Aqueous Zinc-Ion Batteries

Yin,

Li,

Jia

et al. 2024

Inorg. Chem.

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V 2 O 5 undergoes irreversible phase transition and collapse of layered structure during the Zn 2+ insertion/extraction, which severely limits its application as a cathode for aqueous zinc-ion batteries (AZIBs). Herein, a synergistic strategy of conductive polyaniline insertion and graphene composite was proposed to boost the Zn 2+ storage performance of the V 2 O 5 cathode. A square-shaped polyaniline (PANI)-intercalated and graphene-composited vanadium oxide (GO/PANI-PVP/ V 2 O 5 ) structure was successfully synthesized via an in situ oxidation/insertion polymerization combined with a hydrothermal method. The results showed that PANI intercalation and the composite of graphene combined with layered V 2 O 5 , enabling reversible intercalation of Zn 2+ /H + . The insertion of conjugated PANI not only increases the lattice spacing of V 2 O 5 , providing a channel for rapid transport of Zn 2+ , but also increases the storage sites for charges through doping/ dedoping processes and redox conversion reactions. GO/PANI-PVP/V 2 O 5 delivers an excellent specific capacity (495 mA h g −1 at 0.1 A g −1 ), wonderful rate capability (208 mA h g −1 at 30 A g −1 ), and good cycling stability (93% after 4000 cycles). Our results provide a new approach for adjusting the valence states, interlayer spacing, and rational design of organic−inorganic compound materials for different functional materials.

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Testing the Stability of NASICON Solid Electrolyte in Seawater Batteries

Iordache,

Oubraham,

Borta

et al. 2024

Energies

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Rechargeable batteries play a crucial role in the utilization of renewable energy sources. Energy storage systems (ESSs) are designed to store renewable energy efficiently for immediate use. The market for energy storage systems heavily relies on lithium-ion batteries due to their high energy density, capacity, and competitiveness. However, the increasing cost and limited availability of lithium make long-term use challenging. As an alternative to Li-ion batteries, rechargeable seawater batteries are gaining attention due to their abundant and complementary sodium ion active materials. This study focuses on the preparation and characterization of Na3.0Zr2Si2PO12- and Na3.15Zr2Si2PO12-type ceramic membranes and testing their stability in seawater batteries used as solid electrolyte. From the surface analysis, it was observed that the Na3.15Zr2Si2PO12 powder showed a specific surface area of 2.94 m2/g compared to 2.69 m2/g for the Na3.0Zr2Si2PO12 powder. The measured NASICON samples achieved ionic conductivities between 7.42 × 10−5 and 4.4 × 10−4 S/cm compared to the NASICON commercial membrane with an ionic conductivity of 3.9 × 10−4 S/cm. Battery testing involved charging/discharging at various constant current values (0.6–2.0 mA), using Pt/C as the catalyst and seawater as the catholyte.

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Interface issues and challenges for NASICON-based solid-state sodium-metal batteries

Cited by 3 publications

References 117 publications

Interfacial Modulation with Phosphorylated Covalent Organic Framework Enabling Highly Durable Sodium Metal Batteries in Carbonate‐Based Electrolytes

Interfacial Modulation with Phosphorylated Covalent Organic Framework Enabling Highly Durable Sodium Metal Batteries in Carbonate‐Based Electrolytes

Engineering Interlayer Space and Composite of Square-Shaped V₂O₅ by PVP-Assisted Polyaniline Intercalation and Graphene for Aqueous Zinc-Ion Batteries

Testing the Stability of NASICON Solid Electrolyte in Seawater Batteries

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Interface issues and challenges for NASICON-based solid-state sodium-metal batteries

Cited by 3 publications

References 117 publications

Interfacial Modulation with Phosphorylated Covalent Organic Framework Enabling Highly Durable Sodium Metal Batteries in Carbonate‐Based Electrolytes

Interfacial Modulation with Phosphorylated Covalent Organic Framework Enabling Highly Durable Sodium Metal Batteries in Carbonate‐Based Electrolytes

Engineering Interlayer Space and Composite of Square-Shaped V2O5 by PVP-Assisted Polyaniline Intercalation and Graphene for Aqueous Zinc-Ion Batteries

Testing the Stability of NASICON Solid Electrolyte in Seawater Batteries

Contact Info

Product

Resources

About

Engineering Interlayer Space and Composite of Square-Shaped V₂O₅ by PVP-Assisted Polyaniline Intercalation and Graphene for Aqueous Zinc-Ion Batteries