Low temperature plasma treatment experiments were conducted on AS4 and AU4 type fibers in the presence of air, argon and nitrogen to study their effects on the resulting fiber-matrix adhesion in the composites fabricated with the fibers. Optimum conditions for the introduction of maximum surface oxygen and nitrogen functional groups on AS4 and AU4 fiber surfaces were derived. X-ray photelectron spectroscopy was performed on the fiber surfaces to determine the effect of plasma treatment on the amount and types of surface functional groups introduced. Scanningelectron microscopy was performed on the fiber surfaces and the amount of surface etching and pitting was correlated to the plasma treatment conditions. Transverse tensile specimens were fabricated from treated fibers representing a few plasma treatment conditions, and their transverse tensile strengths were measured experimentally. An attempt was made to determine the effects offactors such as amount ofchemical groups on the fiber surfaces, mechanical interlocking, molecular level entanglement and physical interactions to explain the data.
KEY WORDS matrix adhesion; transverse tensile strength.Low temperature plasma; carbon fibers; composites; surface functional groups; fiber-
INTRODUCTIONThe technological demand for materials that exhibit improved specific strength and stiffness characteristics has led to considerable research and development in the field of fiber-reinforced resin-matrix composites. When fibers such as carbon, boron, and glass are combined with various epoxy, polyester, and polyamide resins, they produce a class of materials possessing specific tensile properties that can exceed those of the best metal alloys currently in production, depending on the fiber-matrix combination. By using specific combinations of fiber and matrix, it is possible to tailor structural materials that are superior for specific applications.Among the types of fibers, carbon is used for large-volume commercial applications based on three significant advantages. They are a) stiffer, b) lighter, and c) corrosion resistant in certain environments where glass fibers are vulnerable. However, the Downloaded by [North Carolina State University] at 21:19 09 April 2015 2 N. P. VAIDYANATHAN et al.potential for carbon fiber reinforced composites is limited by their low transverse mechanical properties that are directly attributed to the poor adhesion between the fibers and the matrix. The adhesion between untreated carbon fibers and epoxy matrices has generally been poor. Therefore, it is important that the fiber surface have certain qualities that enhance its adhesion, which are: a) a large external surface area free from superficial defects, b) a high degree of roughness, and c) sufficient number of surface functional groups.,The objective of this work was to study the effect of low temperature plasma treatment of carbon fibers on the enhancement of surface oxygen and nitrogen functional groups on AS4 and A U 4 type carbon fibers. Initial studies were also conducted to examine...