“…The overuse of fossil fuels can cause the current energy shortage and irreversible environmental damage. In order to reduce the unrestrained consumption of nonrenewable resources, the clean energy (e.g., H 2 ) production by photocatalytic water splitting can be considered a promising way to solve the above issues. − At present, many types of photocatalysts have been found, such as metal oxides (TiO 2 , ln 2 O 3 , Fe 2 O 3 , etc), metal sulfides (CdS, CdZnS, ZnIn 2 S 4 , etc), and carbon materials (carbon dots, carbon nitride, carbon nanotube, etc). Among these photocatalysts, the hexagonal ZnIn 2 S 4 , as a ternary chalcogenide with unique 2D layered structure, appropriate band gap, and robust resistance to photocorrosion, is one of the most favorable catalyst for photocatalytic H 2 generation under visible-light illumination .…”