Intercalation of silver atoms under a graphite monolayer on Ni(111)

Starodubov, A. V.; Medvetskii, M. A.; Shikin, A. M.; Adamchuk, V. K.

doi:10.1134/1.1778462

Cited by 46 publications

(37 citation statements)

References 19 publications

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“…The deposition/annealing process is iterated until no trace of parabolic π band is observed. Further Ag deposition and annealing does not lead to a change in the electronic structure suggesting that the intercalation process may be limited to a single-layer of noble atoms, in agreement with earlier results [15][16][17]23 . DFT calculations were performed with the Vienna ab-initio simulation package (VASP) 24,25 .…”

Section: Methodssupporting

confidence: 91%

Hybridization of graphene and a Ag monolayer supported on Re(0001)

et al. 2013

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We have investigated the electronic structure of graphene supported on Re(0001) before and after the intercalation of one monolayer of Ag by means of angle-resolved photoemission spectroscopy measurements and density functional theory calculations. The intercalation of Ag reduces the graphene-Re interaction and modifies the electronic band structure of graphene. Although the linear dispersion of the π state of graphene in proximity of the Fermi level highlights a rather weak graphene-noble metal layer interaction, we still observe a significant hybridization between the Ag bands and the π state in lower energy regions. These results demonstrate that covering a surface with a noble metal layer does decouple the electronic states, but still leads to a noticeable change in the electronic structure of graphene.

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Section: Methodssupporting

confidence: 91%

Hybridization of graphene and a Ag monolayer supported on Re(0001)

et al. 2013

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“…1(b) is characterized by the peaks of Ni d states at the binding energies of 0.5 and 1.5 eV and a strongly pronounced peak of graphene p states at the binding energy of $10 eV. Large binding energy shift of the peak of graphene p states (as compared to graphite or freestanding graphene) indicates a strong interaction between the graphene and the Ni substrate [11,12,[20][21][22][23][24][25][26][27][28][29][30][31]. Weak features at the binding energy of $4.5 eV corresponding to r states of graphene can also be distinguished in the spectrum.…”

Section: 1mentioning

confidence: 99%

Spin splitting of Dirac fermions in graphene on Ni intercalated with alloy of Bi and Au

Жижин

Varykhalov

Рыбкин

et al. 2015

Carbon

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“…It is known that adsorbed metals-not only transition metals, but also other types of metals-can be buried beneath sheets of supported graphene, e.g. [68][69][70][71][72][73]. It is also known that some non-transition metals can intercalate in graphite surfaces, e.g.…”

Section: Bonding Of a Metal Adatom To The Basal Planementioning

confidence: 99%

Transition metals on the (0 0 0 1) surface of graphite: Fundamental aspects of adsorption, diffusion, and morphology

Appy

Lei

Wang

et al. 2014

Progress in Surface Science

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In this article, we review basic information about the interaction of transition metal atoms with the (0001) surface of graphite, especially fundamental phenomena related to growth. Those phenomena involve adatomsurface bonding, diffusion, morphology of metal clusters, interactions with steps and sputter-induced defects, condensation, and desorption. General traits emerge which have not been summarized previously. Some of these features are rather surprising when compared with metal-on-metal adsorption and growth. Opportunities for future work are pointed out. Chemistry | Materials Science and Engineering | PhysicsComments NOTICE: This is the author's version of a work that was accepted for publication in Progress in Surface Science. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publications. A definitive version was subsequently published in Progress in Surface Science, 89 (2014), doi: 10.1016/j.progsurf.2014.08.001. AuthorsDavid Victor Appy, Huaping Lei, Cai-Zhuang Wang, Michael C. Tringides, Da-Jiang Liu, James W. Evans, and Patricia A. Thiel This article is available at Iowa State University Digital Repository: http://lib.dr.iastate.edu/chem_pubs/99 1 NOTICE: This is the author's version of a work that was accepted for publication in Progress in Surface Science. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publications. A definitive version was subsequently published in Progress in Surface Science, 89 (2014) Abstract.In this article, we review basic information about the interaction of transition metal atoms with the (0001) surface of graphite, especially fundamental phenomena related to growth. Those phenomena involve adatom-surface bonding, diffusion, morphology of metal clusters, interactions with steps and sputter-induced defects, condensation, and desorption. General traits emerge which have not been summarized previously. Some of these features are rather surprising when compared with metal-onmetal adsorption and growth. Opportunities for future work are pointed out. 1.Introduction.Graphite is an intriguing support for metals because of its inertness in aggressive environments, as well as its low cost and high abundance. A major application for graphite-supported metals is lithium ion batteries [1,2]. In fact, the demand for these batteries is expanding so quickly that it currently drives the international market in graphite [1]. An important application on the horizon is biofuel conversion, where graphite (or other carbon-based materials) may provide robust supports for catalysts in aqueous media [3].Adsorption of transition metals and noble metals on graphite has been studi...

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Intercalation of silver atoms under a graphite monolayer on Ni(111)

Cited by 46 publications

References 19 publications

Hybridization of graphene and a Ag monolayer supported on Re(0001)

Hybridization of graphene and a Ag monolayer supported on Re(0001)

Spin splitting of Dirac fermions in graphene on Ni intercalated with alloy of Bi and Au

Transition metals on the (0 0 0 1) surface of graphite: Fundamental aspects of adsorption, diffusion, and morphology

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