Interactions of neutral phosphonate esters with metal halides

Mikulski, Chester M.; Karayannis, Nicholas M.; Minkiewicz, J. V.; Pytlewski, L.L.; Labes, M. M.

doi:10.1016/s0020-1693(00)92545-3

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V206(s) + 2rpo(oh)2(soln) + 3c2h5oh2

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2009

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Cited by 44 publications

(19 citation statements)

References 21 publications

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“…In related reactivity studies using the isomeric dibromides, CpRe(CO)2Br2, we have observed that a direct metathetical re- (1) Nesmeyanov, A. N.; Kolobova, N. E.; Makarov, Y. V.; Anisimov, K.…”

Section: Introductionmentioning

confidence: 95%

Reduction pathways in lateral and diagonal (.eta.5-C5Me5)Re(CO)2Br2. Synthesis, structure, and reactivity of [(.eta.5-C5Me5)Re(CO)2Br-]

Nunn¹,

Cowley²,

Lee³

et al. 1990

Inorg. Chem.

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Section: Introductionmentioning

confidence: 95%

Reduction pathways in lateral and diagonal (.eta.5-C5Me5)Re(CO)2Br2. Synthesis, structure, and reactivity of [(.eta.5-C5Me5)Re(CO)2Br-]

Nunn¹,

Cowley²,

Lee³

et al. 1990

Inorg. Chem.

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“…2V0RP03-H20.C2H60H(s) + CH3CHO + H20 (1) Previous work has shown6 that when R is an n-alkyl or an aryl group such as phenyl or p-methoxyphenyl, one molecule of ethanol per formula unit is included in the product. This alcohol is subject to exchange reactions with other alcohols and with water.…”

Section: V206(s) + 2rpo(oh)2(soln) + 3c2h5ohmentioning

confidence: 99%

“…Vanadyl benzylphosphonate (1) is obtained as a mixture of two phases, one with a layer spacing of 12.0 A and the other with a layer spacing of 8.9 A. The ethanol-containing phase, V0(C6H5CH2P03)-H20*C2H50H, has the larger layer spacing.…”

Section: V206(s) + 2rpo(oh)2(soln) + 3c2h5ohmentioning

confidence: 99%

Vanadyl benzylphosphonates and vanadyl naphthylphosphonates: intercalation reactions with butanols

Johnson¹,

Brody²,

Alexander³

et al. 1990

Chem. Mater.

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“…UZC^GIuCuN* FeCl2 or FeCl3 (100 mM) were added at a molar ratio of 0.8 versus 1 and sonicated. Transparent composite films were obtained by spreading the dispersions onto fluorocarbon sheets and allowing them to stand at 25 °C in 60% relative humidity for 2 days.…”

mentioning

confidence: 99%

“…Such compounds exhibit interesting sorption and catalytic properties and serve as models for organic/inorganic interfaces. 1,2 Vanadyl organophosphonates have been shown to intercalate alcohols by coordination of the intercalating molecule to the vanadium atom in the inorganic vanadium phosphate layer.1 23 Previous interpretation of the mechanisms of these intercalation reactions has relied on assessment of the variation in unit cell dimensions determined by powder X-ray diffraction data as both the size of the organic group attached to phosphorus and the intercalating alcohol molecule were varied. Detailed structural information has been unavailable due to the lack of suitable single crystals for X-ray analysis, despite numerous and varied attempts at crystal growth.…”

mentioning

confidence: 99%