Self-assembled
monolayers of corrosion inhibitors of the mercaptobenzimidazole
family, SH-BimH, SH-BimH-5NH2, and SH-BimH-5OMe, were formed
on template-stripped ultraflat Au surfaces using microcontact printing,
and subsequently analyzed using X-ray photoelectron spectroscopy (XPS),
atomic force microscopy (AFM), and AFM-force spectroscopy (AFM-FS)
using a quantitative imaging (QI) mode. Printing of all used inhibitor
molecules resulted in clear patterns and in slightly more compact
films compared to immersion. The stability of the monolayers is further
probed by AFM-FS. Adhesion values of laterally heterogeneous inhibitor-modified
surfaces compared to bare Au surfaces, nonpatterned areas, and fully
covered surfaces are analyzed and discussed. Microcontact printing
confers a superior nanomechanical stability to imidazole-modified
films of the printed surface patches as compared to homogeneously
covered surfaces by immersion into the inhibitor solution.