Inter-Rydberg laser spectroscopy of ArKr

Kane, Daniel J.; Eden, J. G.

doi:10.1016/0009-2614(88)87091-x

Cited by 6 publications

(3 citation statements)

References 23 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Alternate solutions to this problem include the generation of tunable, coherent, and monochromatic VUV light by four-wave mixing for single-photon studies 43 or the method of inter-Rydberg laser spectroscopy pioneered by Eden and co-workers. 44 …”

Section: Discussionmentioning

confidence: 99%

Analysis of the mass-resolved two-photon spectra of jet-cooled ArKr near Kr(5p) and Ar(4s)

Lipson

Dimov

Bascal

et al. 1996

The Journal of Chemical Physics

View full text Add to dashboard Cite

Articles you may be interested inMassresolved multiphoton ionization spectroscopy of jetcooled Cl2. II. The (2+1) REMPI spectrum between 76 000 and 90000 cm−1 New ͑2ϩ1͒ resonantly enhanced multiphoton ionization ͑REMPI͒ spectra of ArKr in the region of Kr*(5p) and Ar*(4s) between Ϸ92378.8 and 94250.7 cm Ϫ1 are presented. A time-of-flight ͑TOF͒ mass spectrometer was used to obtain single isotopomer data. Four band systems, two previously observed by Dehmer and Pratt ͓J. Chem. Phys. 88, 4139 ͑1988͔͒, and two new ones, have been vibrationally analyzed. Excited state bond lengths have been found from Franck-Condon factor calculations while electronic symmetries were assigned from REMPI spectra recorded with circularly polarized light. Our excited state symmetry assignments differ from those recently proposed by Heck et al. ͓J. Phys. Chem. 99, 17700 ͑1995͔͒. The unusual vibrational band intensity distributions observed for some of the electronic systems are rationalized qualitatively in terms of interstate avoided crossings.

show abstract

Section: Discussionmentioning

confidence: 99%

Analysis of the mass-resolved two-photon spectra of jet-cooled ArKr near Kr(5p) and Ar(4s)

Lipson

Dimov

Bascal

et al. 1996

The Journal of Chemical Physics

View full text Add to dashboard Cite

show abstract

“…Sl.3.3 The experinlental data. -In reference [245], using the inter-Rydberg spectroscopy method, the interaction of excited Kr atoms and Ar atoms is investigated. The experiment was carried out at room temperature for the Kr-Ar mixture.…”

mentioning

confidence: 99%

“…The identification of electron Kr* -Ar quasimolecular states, which participate in absorption, is also presented in [245]. The high-lying Rydberg state has an ion core in the 2n3/2 state and belongs to the Kr (4p56p) -Ar configuration.…”

mentioning

confidence: 99%