Integrated Assessment of Affinity to Chemical Fractions and Environmental Pollution with Heavy Metals: A New Approach Based on Sequential Extraction Results

Abstract

To assess the affinity degree of heavy metals (HMs) to geochemical phases, many indices with several limitations are used. Thus, this study aims to develop a new complex index for assessing contamination level and affinity to chemical fractions in various solid environmental media. For this, a new integrated approach using the chemical affinity index (CAF) is proposed. Comparison of CAF with %F on the literature examples on fractionation of HMs from soils, bottom sediments, atmospheric PM10, and various particle size fractions of road dust proved a less significant role of the residual HMs fraction and a greater contribution of the rest of the chemical fractions in the pollution of all studied environments. This fact is due to the normalization relative to the global geochemical reference standard, calculations of contribution of an individual element to the total pollution by all studied HMs, and contribution of the particular chemical fraction to the total HMs content taken into account in CAF. The CAF index also shows a more significant role in pollution and chemical affinity of mobile and potentially mobile forms of HMs. The strong point of CAF is the stability of the obtained HM series according to the degree of chemical affinity and contamination. Future empirical studies are necessary for the more precise assessment of CAF taking into account the spatial distribution of HMs content, geographic conditions, geochemical factors, the intensity of anthropogenic impact, environmental parameters (temperature, humidity, precipitation, pH value, the content of organic matter, electrical conductivity, particle size distribution, etc.). The combined use of CAF along with other indices allows a more detailed assessment of the strength of HMs binding to chemical phases, which is crucial for understanding the HMs’ fate in the environment.