Integral Skin Foams Based on Polymeric Isocyanates

Rice, D. Marvin

doi:10.1177/0021955x7100700103

Cited by 3 publications

(6 citation statements)

References 2 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Instead inert blowing agents, which migrate away from the skin zone to provide a dense non-porous skin, are recommended with polyamine added to the formulation to provide foam strength (3,10,11,12,13). and breathable skins.…”

Section: Formulation Componentsmentioning

confidence: 99%

“…Crosslinker-The use and effects of a wide range of low MW per reactive site crosslinkers have been described in detail elsewhere (2,3,10,11,12,13,19). It may be necessary to introduce such crosslinkers into a formulation in order to obtain good strength properties and high ILD values at low densities.…”

Section: Formulation Componentsmentioning

confidence: 99%

“…E. Catalyst-Tertiary amines are usually used to catalyze AC foams (2,11,12,13,19); however, incorporating organotin complexes has been reported (3,12,13,19). In general, it is not ad- (12,13,19), and a general review of catalytic activity is available (20). We have found that DABCO@ WT, a recent introduction by Houdry Process Company, is an excellent catalyst for AC foams because it provides an extended cream time but still permits rapid rise and gelation.…”

Section: Formulation Componentsmentioning

confidence: 99%

“…Several patents have issued on the AC process ( 5, 6, 7). The development of &dquo;integral skin&dquo; (IS) foams has also received considerable attention by the Urethane industry (1,2,3,8,9,10,11,12,13), and patents have issued on procedures and techniques for preparing such articles (14,15,16,17,18). The possibility of preparing a finished part in a single operation is very attractive.…”

mentioning

confidence: 99%

“…A water blown foam will be firmer than a water/R-11 blown foam at the same density. Since the current trend in AC foams is toward high ILDs at low densities, water is the recommended blowing agent.Water should not be used in IS foams as C02 formation in the high density skin zone causes defects and porosity (3,10,11,12,13). Instead inert blowing agents, which migrate away from the skin zone to provide a dense non-porous skin, are recommended with polyamine added to the formulation to provide foam strength (3,10,11,12,13).…”

mentioning

confidence: 99%

See 4 more Smart Citations

Polyols and Requirements for Ambient Cure Foams

Powell

Puig

Leuwen

1972

Journal of Cellular Plastics

View full text Add to dashboard Cite

Introduction flexible and semi-rigid urethane foam formulations which generate sufficient exotherm to quickly cure (5-15 minutes) molded foam have received considerable attention by the Urethane industry. Whether termed &dquo;cold cure&dquo; (1), &dquo;cold mold&dquo;, &dquo;ambient cure&dquo;, &dquo;quick strip&dquo; (2) or &dquo;high resiliency&dquo;, they have one ingredient in commona reactive polyol of relatively high molecular weight. Possible cost savings a simplified molding operation (1, 2, 3, 4) might afford added impetus to early development work. Further, the excellent resiliency, comfort (4) and fatigue resistance low density &dquo;ambient cure&dquo; (AC) foams offer are considered very desirable. It is now generally recognized quality molds are necessary for efficient operation and post cure may be necessary to attain suitable strength properties and/or full properties in a reasonable period of time. Rapid mold cycle times are a real advantage in any event. Several patents have issued on the AC process ( 5, 6, 7). The development of &dquo;integral skin&dquo; (IS) foams has also received considerable attention by the Urethane industry (1,2,3,8,9,10,11,12,13), and patents have issued on procedures and techniques for preparing such articles (14,15,16,17,18). The possibility of preparing a finished part in a single operation is very attractive. However, the tendency of urethane foams to discolor and the difficulty of getting low density, resilient IS foams have limited their utility. Generally, trichloromonofluoromethane is used to &dquo;blow&dquo; such foams and high concentrations of polyamines are added to provide urea linkages. Most IS formulations &dquo;ambient cure&dquo;, and, with the above exceptions, most IS foams are formulated like other AC foams.The manufacture of AC molded, and also slab stock foam, especially low density resilient foam, is predicted to increase sharply. The purpose of this report is to summarize the effect of formulation variables on AC foam properties with special attention given to the structure and composition of the polyether component. Although AC foams have the good properties previously mentioned, they do exhibit comparatively poor tear and elongation, high compression set and borderline humid aging resistance. In addition, the formulations are often This paper was originally presented at the SPI Cellular Plastics in Furniture and Home Furnishings Conference on September 14, 15 and 16, 1971. As a Conference Paper, it has not been subjected to the Journal's normal review procedures but is reprinted here as a service to our subscribers. surfactant sensitive (19) and display long tack free time in slab pours. Special attention will be given these problem areas, and, to do this efflciently, it will be assumed the general property trends observed in low density AC, semi-rigid AC and IS foams are correlatable. Formulation ComponentsA. Isocyanate-Toluene diisocyanate (TDI-usually a blend containing 80 to of the 2,4 and 20 % of the 2,6 isomers), crude TDIs of varying compos...

show abstract

Section: Formulation Componentsmentioning

confidence: 99%