We have observed the process of associative ionization (AI) in
collisions between hydrogen and rare gas atoms both prepared in
their ground states (H + X⟶XH+ + e- with
X = Ar,Kr,Xe). This is the first experimental observation
of this process, which we compare to the other charge-producing
cross sections reported previously. AI takes
place only in a small region of collision energies close to
threshold. The cross sections show a distinct maximum, with a
typical value of about 2×10-19 cm2. In contrast to
the heavier rare gases AI is not observed in
collisions of atomic hydrogen with He and Ne.