2017
DOI: 10.1021/acs.jafc.6b05772
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Insights into the Formation and Structures of Starch–Protein–Lipid Complexes

Abstract: The aim of the present study was to characterize the multiscale structures of ternary complexes of a model system of starch, fatty acid (FA), and β-lactoglobulin (βLG) prepared using a Rapid Visco Analyzer (RVA). The addition of βLG to starch-lauric acid or starch-oleic acid RVA pastes resulted in the increased intensity or occurrence of a new viscosity peak during cooling when the RVA protocol was repeated. The viscosity peak was attributed to the formation of starch-βLG-FA complexes. Differential scanning ca… Show more

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Cited by 134 publications
(122 citation statements)
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“…These changes could be attributed to the presence of gluten restrict water supply to a starch molecule for swelling and gelatinization. A similar observation was made by Wang, Zheng, Yu, Wang, and Copeland (2017) who reported that due to the presence of water‐soluble β lactoglobulin in the gel mixture of maize starch − β lactoglobulin decrease the water availability to starch. In BCBs samples gelatinization temperature (57.33–67.46) did not show a significant difference in transition temperature but there is decreased in the gelatinization enthalpy (2.24–2.66 J/g) to that of WS.…”
Section: Resultssupporting
confidence: 82%
See 1 more Smart Citation
“…These changes could be attributed to the presence of gluten restrict water supply to a starch molecule for swelling and gelatinization. A similar observation was made by Wang, Zheng, Yu, Wang, and Copeland (2017) who reported that due to the presence of water‐soluble β lactoglobulin in the gel mixture of maize starch − β lactoglobulin decrease the water availability to starch. In BCBs samples gelatinization temperature (57.33–67.46) did not show a significant difference in transition temperature but there is decreased in the gelatinization enthalpy (2.24–2.66 J/g) to that of WS.…”
Section: Resultssupporting
confidence: 82%
“…The effect of the supply of different lipid sources to WS on complex formation and their short‐range molecular order structures were evaluated by Raman spectroscopy. It is reported that full width at half maximum (FWHM) at 480 cm −1 of Raman spectra can be used to indicate the order structure formation in starch, with lower FWHM value and high absorption intensity at this wavelength indicative of more firm complex formation (Wang et al., 2017). The Raman spectra and FWHM value at 480 cm −1 of WS, WS–WG and BCBs samples are shown in Figure 1 and Table 4.…”
Section: Resultsmentioning
confidence: 99%
“…The peak at around 20° (2θ) found in all dough is assigned to endogenous starch–lipid complex (Guo et al, ). After steaming, the original A‐type crystalline pattern was lost and a distinct peak emerged at around 20° (2θ) in all steamed bread samples (Figure b); this peak corresponds to the V‐type crystalline pattern due to the formation of starch–lipid or starch–protein–lipid complexes during heating (Wang, Zheng, Yu, Wang, & Copeland, ). The relative crystallinities of all steamed bread samples were not observed, consistent with the reports of Xu, Xu, Wang, and Zhou ().…”
Section: Resultsmentioning
confidence: 99%
“…Increases in peak viscosity for starch isolated from rice grains were observed for heated air (40, 100, and 70–110 °C) and for the flour when the grains were dried by intermittent drying (Table ). The reduction in peak viscosity is due to the reduced capacity of the starch granules to absorb water before a physical collapse . Cruz et al reported that starch isolated from sorghum grains and drying temperatures of 45, 65, and 85 °C had no change in peak viscosity.…”
Section: Resultsmentioning
confidence: 99%
“…Yue and Elias observed increases in the breakdown, peak viscosity, and final viscosity, at higher temperatures (90 °C) on isolated pasta starch, dried at low, high, and ultra‐high temperatures. Cruz et al observed a decrease in breakdown when drying at air temperatures of 85 °C in starch isolated from sorghum and the behavior of rice grains with red pericarp (flour) was different and can be attributed to the presence of other components of the pericarp, such as proteins, which promote interactions with the starch granules . The reduction of the final viscosity and breakdown of the starch at higher temperatures (Table ) is associated with a decrease in swelling power and solubility (Table ).…”
Section: Resultsmentioning
confidence: 99%