Insights into a novel class of azobenzenes incorporating 4,6-<i>O</i>-protected sugars as photo-responsive organogelators

Bhavya, P.; Jenifer, V. Rabecca; Muthuvel, Panneerselvam; Das, Thangamuthu Mohan

doi:10.1039/c9ra08033c

Cited by 3 publications

(2 citation statements)

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“…These aromatic solvents, which are a major cause of pollution, have received significantly less attention in the past, 41 especially when compared to petroleum oils, which have been examined extensively. 42 In the literature analogous compounds of LMOGs have been reported 1 43 and 2 44 (Fig. 1).…”

Section: Introductionmentioning

confidence: 68%

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Smart supramolecular photoresponsive gelator with long-alkyl chain azobenzene incorporated sugar derivatives for recycling aromatic solvents and sequestration of cationic dyes

Jenifer

Thangamuthu

2022

Soft Matter

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Section: Introductionmentioning

confidence: 68%

“…All the compounds were synthesized by simple processes involving few-step based on our previous reports 44,61 with slight modifications. The synthetic route of gelators is shown in Scheme S1 (ESI‡).…”

Section: Methodsmentioning

confidence: 99%

Smart supramolecular photoresponsive gelator with long-alkyl chain azobenzene incorporated sugar derivatives for recycling aromatic solvents and sequestration of cationic dyes

Jenifer

Thangamuthu

2022

Soft Matter

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A C₃-symmetrical tripodal acylhydrazone organogelator for the selective recognition of cyanide ions in the gel and solution phases: practical applications in food samples

2020

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Emerging Aspects of Triazole in Organic Synthesis: Exploring its Potential as a Gelator

Das

Jenifer

Pradhan

2024

COS

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Cu(I)-catalyzed azide−alkyne 1,3-dipolar cycloaddition (CuAAC) — commonly known as the “click reaction” — serves as the most effective and highly reliable tool for facile construction of simple to complex designs at the molecular level. It relates to the formation of carbon heteroatomic systems by joining or clicking small molecular pieces together with the help of various organic reactions such as cycloaddition, conjugate addition, ring-opening, etc. Such dynamic strategy results in the generation of triazole and its derivatives from azides and alkynes with three nitrogen atoms in the five-membered aromatic azole ring that often form gel assembled structures having gelating properties. These scaffolds have led to prominent applications in designing advanced soft materials, 3D printing, ion sensing, drug delivery, photonics, separation, and purification. In this review, we mainly emphasize on the different mechanistic aspects of triazole formation which includes synthesis of sugar-based and non-sugar-based triazoles, and their gel applications reported in the literature for the past ten years, as well as the upcoming scope in different branches of applied sciences.

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Insights into a novel class of azobenzenes incorporating 4,6-O-protected sugars as photo-responsive organogelators

Abstract: A novel class of 4,6-O-butylidene/ethylidene/benzylidene β-d-glucopyranose gelator functionalized with photo-responsive azobenzene moieties were designed and synthesized and also characterized using different spectral techniques.

Cited by 3 publications

References 65 publications

Smart supramolecular photoresponsive gelator with long-alkyl chain azobenzene incorporated sugar derivatives for recycling aromatic solvents and sequestration of cationic dyes

Smart supramolecular photoresponsive gelator with long-alkyl chain azobenzene incorporated sugar derivatives for recycling aromatic solvents and sequestration of cationic dyes

A C₃-symmetrical tripodal acylhydrazone organogelator for the selective recognition of cyanide ions in the gel and solution phases: practical applications in food samples

Emerging Aspects of Triazole in Organic Synthesis: Exploring its Potential as a Gelator

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Insights into a novel class of azobenzenes incorporating 4,6-O-protected sugars as photo-responsive organogelators

Abstract: A novel class of 4,6-O-butylidene/ethylidene/benzylidene β-d-glucopyranose gelator functionalized with photo-responsive azobenzene moieties were designed and synthesized and also characterized using different spectral techniques.

Cited by 3 publications

References 65 publications

Smart supramolecular photoresponsive gelator with long-alkyl chain azobenzene incorporated sugar derivatives for recycling aromatic solvents and sequestration of cationic dyes

Smart supramolecular photoresponsive gelator with long-alkyl chain azobenzene incorporated sugar derivatives for recycling aromatic solvents and sequestration of cationic dyes

A C3-symmetrical tripodal acylhydrazone organogelator for the selective recognition of cyanide ions in the gel and solution phases: practical applications in food samples

Emerging Aspects of Triazole in Organic Synthesis: Exploring its Potential as a Gelator

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A C₃-symmetrical tripodal acylhydrazone organogelator for the selective recognition of cyanide ions in the gel and solution phases: practical applications in food samples