“…Surprisingly, no other significant efforts in order to get additional insight into these experimental observations have been presented since then, until recently in a research work carried out by our group. 9 Nowadays, with the advent of more robust phenomenological models, formulated in the past two decades, [10][11][12][13] have finally provided a framework allowing to revisit this issue. Next, it is briefly described the rationalization of the prototypical ligand-tometal charge transfer (LMCT) state O 2−/− → Eu 3+/2+ in Eu-doped oxides under this phenomenological approach.…”
The coloring of oxides doped with Ln 4+ has been the subject of much scientific research related to its application as pigments. However, until now, a rational explanation of this phenomenon had not been presented. Here is shown a scheme from a phenomenological perspective, that allows us to rationalize the experimental observations in the optical absorption spectra of Lndoped (Ln = Ce, Pr and Tb) Y 2 O 3 and Y 4 Zr 3 O 12 . This analysis was based on the explanation of the ligand-to-metal charge transfer (LMCT) O 2−/− → Eu 3+/2+ state in Eu-doped oxides. In this sense, Eu-doped Y 2 O 3 and Y 4 Zr 3 O 12 characterization is also presented. Features in the absorption spectra of these materials confirm the presence of Ce 4+ , Pr 4+ and Tb 4+ , and the photoluminescent spectra their respective trivalent oxidation states. To demonstrate the contribution of multiple LMCT O 2−/− → Ln 4+/3+ states to the absorption spectra of compounds, Gaussian deconvolutions were performed. Maxima of Gaussian peak profiles were guessed from a vacuum referred binding energy diagram. The initial state for each LMCT O 2−/− → Ln 4+/3+ is always the top of the valence band, while the final ones correspond to some Ln 3+ f state. Additional required peaks to reach adequate fittings were assigned to IVCT Ln 3+ / 4+ and f-d Ln 3+ states.
“…Surprisingly, no other significant efforts in order to get additional insight into these experimental observations have been presented since then, until recently in a research work carried out by our group. 9 Nowadays, with the advent of more robust phenomenological models, formulated in the past two decades, [10][11][12][13] have finally provided a framework allowing to revisit this issue. Next, it is briefly described the rationalization of the prototypical ligand-tometal charge transfer (LMCT) state O 2−/− → Eu 3+/2+ in Eu-doped oxides under this phenomenological approach.…”
The coloring of oxides doped with Ln 4+ has been the subject of much scientific research related to its application as pigments. However, until now, a rational explanation of this phenomenon had not been presented. Here is shown a scheme from a phenomenological perspective, that allows us to rationalize the experimental observations in the optical absorption spectra of Lndoped (Ln = Ce, Pr and Tb) Y 2 O 3 and Y 4 Zr 3 O 12 . This analysis was based on the explanation of the ligand-to-metal charge transfer (LMCT) O 2−/− → Eu 3+/2+ state in Eu-doped oxides. In this sense, Eu-doped Y 2 O 3 and Y 4 Zr 3 O 12 characterization is also presented. Features in the absorption spectra of these materials confirm the presence of Ce 4+ , Pr 4+ and Tb 4+ , and the photoluminescent spectra their respective trivalent oxidation states. To demonstrate the contribution of multiple LMCT O 2−/− → Ln 4+/3+ states to the absorption spectra of compounds, Gaussian deconvolutions were performed. Maxima of Gaussian peak profiles were guessed from a vacuum referred binding energy diagram. The initial state for each LMCT O 2−/− → Ln 4+/3+ is always the top of the valence band, while the final ones correspond to some Ln 3+ f state. Additional required peaks to reach adequate fittings were assigned to IVCT Ln 3+ / 4+ and f-d Ln 3+ states.
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