Insight into the adsorptive removal of ibuprofen using porous carbonaceous materials: A review

Ayati, Ali; Tanhaei, Bahareh; Beiki, Hossein; Krivoshapkin, Pavel V.; Krivoshapkina, Elena F.; Tracey, Chantal Talena

doi:10.1016/j.chemosphere.2023.138241

Cited by 44 publications

(19 citation statements)

References 196 publications

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“…125 Their impact on human development and their widespread use have environmental drawbacks since their residual presence in water bodies and soil is a current global concern. 126,127 Among the most concerning pharmaceutical pollutants are those whose degradation is slower and those whose activity can directly affect wildlife and plants, and examples of these are non-steroidal anti-inflammatory drugs, antibiotics, beta-blockers (β-blockers), antiepileptic drugs, and blood lipid-lowering agents, antidepressants, hormones, antihistamines, and X-ray contrast media. 128 Traditional treatment methods, such as those found in wastewater treatment plants, can often not completely remove pharmaceutical contaminants.…”

Section: Pharmaceuticals Moleculesmentioning

confidence: 99%

Molecular inspired electrocatalyst materials for environmental remediation

Calvillo Solis,

Castillo,

Yin

et al. 2023

Inorg. Chem. Front.

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Section: Pharmaceuticals Moleculesmentioning

confidence: 99%

Molecular inspired electrocatalyst materials for environmental remediation

Calvillo Solis,

Castillo,

Yin

et al. 2023

Inorg. Chem. Front.

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“…For the adsorption technique, the selection of appropriate materials for removing environmental contaminants (ECs) from water environments is the most important criterion. Adsorbents selected should exhibit large specific surface area, suitable pore size distribution, high mechanical and chemical resistance, feasible reusability, and especially high affinity to adsorbate (especially at low initial pollutant concentrations) (Ayati et al, 2023; Turk Sekulic et al, 2019; Zhuang et al, 2020). In the literature, some natural and synthesized adsorbents were applied for removing naproxen drug from aqueous solution.…”

Section: Introductionmentioning

confidence: 99%

“…ECs consist of different groups, such as pharmaceuticals, personal care products, pesticides, and steroid hormones. Furthermore, non‐steroidal anti‐inflammatory drugs (NSAIDs) are the most widely used pharmaceutical group without a prescription worldwide (Ayati et al, 2023; Smiljanić et al, 2020). Naproxen, which is classified as an acidic analgesic drug of NSAIDs, is used for the treatment of inflammation and fever (Feng et al, 2021; Turk Sekulic et al, 2019).…”

Section: Introductionmentioning

confidence: 99%

“…The molecule dimension of organic naproxen (length × width × height: 1.17 × 0.53 × 0.50 nm) (Karami et al, 2020) is not suitable for diffusing into the micropore network (pore width <2 nm) of materials. Based on pore‐filling mechanism, some authors synthesized mesoporous materials for adsorbing naproxen with different purposes: drug delivery (Beňová et al, 2017; Zauška et al, 2022) and water treatment Ayati et al, 2023).…”

Section: Introductionmentioning

confidence: 99%

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Important role of pore‐filling mechanism in separating naproxen from water by micro‐mesoporous carbonaceous material

Arslan,

Tomul,

Kınaytürk

et al. 2024

Water Environment Research

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Commercial micro‐mesoporous carbonaceous material (MCM; 56.8% mesopores) was applied for investigating the removal phenomenon of naproxen drug in aqueous solutions through batch adsorption experiments. Results demonstrated that the adsorption capacity of MCM to naproxen was slightly affected by different pHeq (2.0–11) and ionic strength (0–1 M NaCl). Adsorption kinetics, isotherms, thermodynamics, and mechanisms were evaluated at pH 7.0. Adsorption kinetics indicated the rate constants for adsorption (0.2 × 10−3 L/(mg × min) and desorption (0.076/min) and the adsorption equilibrium constant (2.6 × 10−3 L/mg). Adsorption isotherm showed that MCM exhibited a high‐affinity adsorption capacity to naproxen (even at low concentrations) and its Langmuir maximum adsorption capacity (Qmax) was 252.7 mg/g at 25°C. Adsorption thermodynamics proved that the adsorption process was endothermic and physisorption (ΔH° = 9.66 kJ/mol). The analysis result of pore size distribution demonstrated that the internal pore structure of MCM was appropriate for adsorbing naproxen molecules. Pore‐filing mechanism (pore diffusion phenomenon) was confirmed by a considerable decrease in BET‐surface area (585 m2/g) and total pore volume (0.417 cm3/g) of MCM after adsorbing naproxen (~1000 mg/L and pH 7.0) at 5 min (341 and 0.256), 60 min (191 and 0.205), 120 min (183 and 0.193), 360 min (144 and 0.175), and 24 h (71.6 m2/g and 0.123 cm3/g, respectively). The pore diffusion occurred rapidly (even at the initial adsorption period of 5 min). The FTIR technique was applied to identify the existence of C–H···π and n–π interaction. π–π interaction (evaluated through ID/IG ratio and C=C band) played a minor contribution in adsorption mechanisms. The ID/IG ratio (determined by the Raman technique) of MCM before adsorption (1.195) was similar to that after adsorption (1.190), and the wavenumber (C=C band; its FTIR spectrum) slightly shifted from 1638 to 1634 cm−1 after adsorption. A decrease in the Qmax value of MCM from 249 to 217 (H2O2‐oxidized MCM) or to 224 mg/g (HNO3‐oxidized MCM) confirmed the presence of π–π interaction. Electrostatic attraction was a minor contribution. MCM can serve as a promising material for removing naproxen from water environment through a pore‐filling mechanism.Practitioner Points Pore‐filling mechanism was proposed by comparing textural properties of MCM before and after adsorbing naproxen. C–H···π and n–π interactions were identified via FTIR technique. π–π interaction was observed by FTIR and Raman techniques. Oxidation of MCM with HNO3 or H2O2 was a helpful method to explore π–π interaction. Electrostatic attraction was explained through studies: effects of pH and NaCl along with desorption.

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“…Although progresses have been made in the application of biomass-derived carbon materials in the adsorption of organic pollutants, relevant reviews are focused on dyes, [71,72] pharmaceuticals, [73][74][75] VOCs, [76] mixed adsorbate systems, [77] bamboo-derived carbon adsorbents, [78,79] fruit waste-derived carbon adsorbents, [80] Eucalyptus-based carbon adsorbents [81] and hydrothermal carbons, [82] rather than a comprehensive summary of the removal of organic pollutants by biomass carbons. Moreover, the modification strategies of carbon adsorbents are rarely reported in above reviews.…”

Section: Introductionmentioning

confidence: 99%

Biomass‐Derived Carbon Materials for the Adsorption of Organic Pollutants

Qiu,

Li,

et al. 2023

Advanced Sustainable Systems

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With the development of economy and increasing environmental awareness, how to effectively remove organic pollutants in wastewater is a research hotspot. Adsorption is one of the effective methods, and the adsorption material is the key factor to determine the efficiency. In this review, biomass‐derived carbon materials as adsorbents of organic pollutants and the adsorption mechanism are discussed in depth. The effects of carbonization and activation on the morphology and structure of carbon materials; the modification strategies of carbon adsorbents, the adsorption performance of biomass‐derived carbon materials for organic pollutants are described and illustrated; the future work of the biomass‐derived carbon materials is proposed.

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Insight into the adsorptive removal of ibuprofen using porous carbonaceous materials: A review

Cited by 44 publications

References 196 publications

Molecular inspired electrocatalyst materials for environmental remediation

Molecular inspired electrocatalyst materials for environmental remediation

Important role of pore‐filling mechanism in separating naproxen from water by micro‐mesoporous carbonaceous material

Biomass‐Derived Carbon Materials for the Adsorption of Organic Pollutants

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