Insight into D-galactose Oxidation: Kinetic and Mechanistic Analysis with Imidazolium Fluorochromate
Ashish Tomar,
Unik Arora,
Jai Veer Singh
Abstract:In a 50% (v/v) aqueous acetic acid medium, a study on the oxidation kinetics of D-galactose by imidazolium fluorochromate (IFC) was conducted. The study revealed unit-order dependence on [D-galactose], [IFC], and [perchloric Acid]. The reaction was catalyzed by perchloric acid, and followed a 1:1 stoichiometric ratio. Adding sodium hyperchlorate (VII) salt did not affect the reaction. Polymerization of acrylonitrile was not observed in the oxidation process. The oxidation rates were retarded on adding Mn2+ ion… Show more
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