Abstract:Stereoselective syntheses of dipicolylamine complexes of Zn, Cu, Ni, and Cd have been achieved by taking advantage of a four‐component dynamic covalent assembly comprising pyridine‐2‐carboxaldehyde, an N‐substituted ethylenediamine, an aliphatic primary alcohol or thiol, and a transition‐metal ion. Zn and Cu selectively bind to the syn forms of the hemiaminal ether ligand whereas Ni and Cd selectively bind to the anti forms. More information can be found in the Full Paper by Raja Angamuthu et al. on page 128 i… Show more
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.