Inside Back Cover: Synthesis, Electronic Structure, and Reactivities of Two‐Sulfur‐Stabilized Carbones Exhibiting Four‐Electron Donor Ability (Chem. Eur. J. 36/2017)

Abstract

Two‐sulfur‐stabilized carbones: the presence of a “second” lone pair on a coordinated atom significantly enhances the electron‐donating ability of the central carbon in carbones. The strongest electron‐donating ability of bis(sulfane)carbon(0) (BSC) among the two‐sulfur‐stabilized carbones was demonstrated by the generation of diprotonated salt BSC⋅H2+. The C‐digold(I) complexes of two‐sulfur‐stabilized carbones provide the first experimental proof of their four‐electron‐donating ability. More information can be found in the Full Paper by T. Fujii et al. on page 8694.