The adsorption of Dyfonate (O-ethyl-S-phenyl ethylphosphonodithioate) was studied on humic acid (HA) saturated with various cations (Fe3+, Al3+, Cu2+, Zn2+, Co2+, Mn2+, Ni2+, Ca2+, Mg2+, and H+). The amount of Dyfonate adsorbed was affected by the cation with which the HA was saturated. The adsorption process could be described empirically by a Freundlich-type isotherm. The K and [Formula: see text] constants of the Freundlich equation decreased and increased, respectively, with increase in temperature. The data suggest a physical type of adsorption.