A collisional radiative model is presented for mercury
discharges with electron temperatures between 0.75-2 eV and electron
densities between 1018-1020 m-3. Such plasma parameters
are encountered in a number of modern light sources, such as
mercury-operated induction lamps and the compact fluorescent lamp. The
analytical top model has been used, which allows the majority of the
non-equilibrium levels to be taken into account implicitly. As a result,
indirect ionization processes involving highly excited atomic mercury
states are taken into account in spite of the relatively low number of
levels (19) which has been considered.
The influence of higher atomic mercury levels on the ionization rate
coefficient has been carefully analysed, and has been found to contribute
significantly. Furthermore, a consistent means of quantifying the
production of radiation by the plasma will be presented by introducing the
specific effective emissivities. These enable one to express the
total radiated power in terms of the densities of the transport-dominated
states and the electron density and temperature. These coefficients, as
well as the net coefficients of ionization and recombination, will be
presented and discussed, enabling their usage in plasma transport models.