Inorganic Fluoride Materials from Solvay Fluor and their Industrial Applications

Juan, Placido Garcia; Swidersky, Hans-Walter; Schwarze, Thomas; Eicher, Johannes

doi:10.1002/9780470660768.ch7

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“…KSnF 3 for the synthesis of highly fluorine-doped SnO 2 nanoparticles [5]. An interesting technical application concerns the use of KSnF 3 and CsSnF 3 as fluxing agent for soldering metal components [6,7].…”

Section: Introductionmentioning

confidence: 99%

¹¹⁹Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF₃ (A = Na, K, Rb, Cs)

Gerke

Tran

Pöttgen

et al. 2015

Zeitschrift Für Naturforschung B

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The complex Sn(II) fluorides ASnF 3 (A = Na, K, Rb, Cs) were synthesized from the alkali fluorides and SnF 2 in methanol through a solvothermal route. Their 119 Sn Mössbauer spectra manifest divalent tin. The isomer shifts range from 3.09 to 2.94 mm s -1 . The pronounced lone-pair character at the Sn(II) centres is expressed by strong electric quadrupole splitting (1.91-1.95 mm s -1 ). The two, respectively four crystallographically independent tin sites in NaSnF 3 , KSnF 3 and RbSnF 3 could not be resolved in the 119 Sn spectra.

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Section: Introductionmentioning

confidence: 99%

¹¹⁹Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF₃ (A = Na, K, Rb, Cs)

Gerke

Tran

Pöttgen

et al. 2015

Zeitschrift Für Naturforschung B

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Inertes Schwefelhexafluorid aktivieren

Zámostná¹,

Braun²

2016

Nachr Chem

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Furnace Brazing Parameters Optimized by Taguchi Method and Corrosion Behavior of Tube-Fin System of Automotive Condensers

Guía-Tello

Trujillo-Vázquez

Pech‐Canul

2017

J. of Materi Eng and Perform

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Inorganic Fluoride Materials from Solvay Fluor and their Industrial Applications

Cited by 4 publications

References 36 publications

¹¹⁹Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF₃ (A = Na, K, Rb, Cs)

¹¹⁹Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF₃ (A = Na, K, Rb, Cs)

Inertes Schwefelhexafluorid aktivieren

Furnace Brazing Parameters Optimized by Taguchi Method and Corrosion Behavior of Tube-Fin System of Automotive Condensers

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Inorganic Fluoride Materials from Solvay Fluor and their Industrial Applications

Cited by 4 publications

References 36 publications

119Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF3 (A = Na, K, Rb, Cs)

119Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF3 (A = Na, K, Rb, Cs)

Inertes Schwefelhexafluorid aktivieren

Furnace Brazing Parameters Optimized by Taguchi Method and Corrosion Behavior of Tube-Fin System of Automotive Condensers

Contact Info

Product

Resources

About

¹¹⁹Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF₃ (A = Na, K, Rb, Cs)

¹¹⁹Sn Mössbauer spectroscopy of solvothermally synthesized fluorides ASnF₃ (A = Na, K, Rb, Cs)