Inorganic Cyclic Silicon-Containing Compounds and Their Organic Derivatives

Андрианов, К. А.; Haiduc, I.; Khananashvili, L. M.

doi:10.1070/rc1963v032n05abeh001339

Cited by 19 publications

(4 citation statements)

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“…Experimental Synthesis: 0.74 g ( 5 mmol) monomeric TMAS, which is synthesized according to Andrianov et al [5] and 8 ginolecular sieve pellets (4 i\, zeolite A. Merck) are tilled into separate compartments of a glass ampoule of 18 mm diameter ( Fig. 1) under argon.…”

Section: Advanced Materialsmentioning

confidence: 99%

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH₃

Jonsen

Löffelholz

1992

Advanced Materials

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Inorganic polymers are attractive precursors for high‐performance ceramics. A new method of producing the polymers via thermal polycondensation of volatile molecular precursors is presented which does not involve the use of catalysts and therefore avoids contamination of the polymers with the catalysts or with byproducts of the catalytic reaction. The example presented is the polycondensation of tetrakis(methylamino)silane, which is a readily available precursor for Si3N4/SiC ceramics.

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Section: Advanced Materialsmentioning

confidence: 99%

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH₃

Jonsen

Löffelholz

1992

Advanced Materials

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“…Compound (48) is one of the thermally and chemically most stable heterosiloxanes. It is solvolysed only slowly by water and alcohols.…”

Section: Propertiesmentioning

confidence: 99%

Recent Development in the Chemistry of Heterosiloxanes

Schmidbaur

1965

Angew. Chem. Int. Ed. Engl.

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Progress in the chemistry of organoheterosiloxanes is reviewed in the light of the latest preparative and spectroscopic results. Attention is focussed on the heterosiloxane structural unit Si-0-X, the bonding in whichdepending on the hetero-atomdiflers characferistically from that in the siloxane bridge Si-0-Si.[7] H. Schmidbaur, Habilitation Thesis, Universitat Marburg, 1964.[ S ] See, for example, E. '4.

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“…Applying this novel procedure to TMAS, the silica analogue Si(NH)-NCH, has been obtained for the first time.Experimental Synthesis: 0.74 g ( 5 mmol) monomeric TMAS, which is synthesized according to Andrianov et al [5] and 8 ginolecular sieve pellets (4 i\, zeolite A. Merck) are tilled into separate compartments of a glass ampoule of 18 mm diameter ( Fig. This reaction proceeds until half of the methylimino bridges are replaced.…”

mentioning

confidence: 99%

Electrochemical deposition and characterization of poly(2,5‐dimethoxyaniline): A new highly conducting polyaniline with enhanced solubility, stability and electrochromic properties

Zotti¹,

Comisso²,

D'Aprano³

et al. 1992

Advanced Materials

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Substituted polyanilines are of interest due to their increased solubility over polyaniline. However, early experiments showed that the substituted materials, while exhibiting a higher solubility (and thus workability), were also less conducting. Here, it is shown that dialkoxy substitution of aniline increases solubility of the polymer while not reducing the conductivity. The lower steric hindrance caused by teh methoxy groups in comparison with methyl groups is thought to be responsible.

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Inorganic Cyclic Silicon-Containing Compounds and Their Organic Derivatives

Cited by 19 publications

References 4 publications

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH₃

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH₃

Recent Development in the Chemistry of Heterosiloxanes

Electrochemical deposition and characterization of poly(2,5‐dimethoxyaniline): A new highly conducting polyaniline with enhanced solubility, stability and electrochromic properties

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Inorganic Cyclic Silicon-Containing Compounds and Their Organic Derivatives

Cited by 19 publications

References 4 publications

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH3

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH3

Recent Development in the Chemistry of Heterosiloxanes

Electrochemical deposition and characterization of poly(2,5‐dimethoxyaniline): A new highly conducting polyaniline with enhanced solubility, stability and electrochromic properties

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Product

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About

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH₃

A new method for thermal polycondensation of volatile molecular precursors—synthesis of polymeric silicon methyldiimide si(NH)NCH₃