Injection of Fluidized Bed Combustion Ash into Mine Workings for Treatment of Acid Mine Drainage

Abstract

A demonstration project was conducted to investigate treating acid mine water by alkaline injection technology (AIT). A total of 379 t of alkaline coal combustion byproduct was injected into in an eastern Oklahoma drift coal mine. AIT increased the pH and alkalinity, and reduced acidity and metal loading. Although large improvements in water quality were only observed for 15 months before the effluent water chemistry appeared to approach pre-injection conditions, a review of the data four years after injection identified statistically significant changes in the mine discharge compared to pre-injection conditions. Decreases in acidity (23%), iron (18%), and aluminum (47%) were observed, while an increase in pH (0.35 units) was noted. Presumably, the mine environment reached quasi-equilibrium with the alkalinity introduced to the system.

Mine Wastes

“…Other rock types (serpentinite; Bernier 2005) and unconventional industrial waste or byproducts such as fly ash from coal power stations or kiln dust from cement factories have been suggested for the treatment of AMD waters (Canty and Everett 2006;Pérez-López et al 2007a, b). However, fly ash commonly contains elevated metal and metalloid concentrations, and its reaction rate is slow compared to lime (Kuyucak 2001).…”