Abstract:Previous research has established that macropores can rapidly transmit water through soil. This observation has raised concern that macropores may also promote rapid movement of agricultural chemicals to groundwater. This is a particular concern for no‐till fields where lack of disruption by tillage can lead to the development of extensive macropore systems. In order to investigate the effect of initial rainfall on chemical transport, strontium bromide hexahydrate (SrBr2·6H2O) and atrazine (2‐chloro‐4‐ethylami… Show more
“…-Whilst a prerequisite for estimation of overall contamination potential, in more detail, relatively more precipitation both before and after pesticide application may serve to decrease resultant groundwater concentrations and thus likelihood for detection. Dilution, increased run-off, decreased soil matrix retainment (Shipitalo et al, 1990) and decreased top-soil cracking (Brown et al, 1995) are potential explanations. More and higher-resolution studies of the effects of precipitation on pesticide contamination potential of groundwater in different environments and in relation to actual pesticide use are needed in order to be able to better and more accurately account for the resultant effects in terms of risk assessment of pesticide contamination of groundwater on different scales.…”
Section: Discussionmentioning
confidence: 99%
“…Other studies who have reported relatively less pesticide transport from wet than from dry soils have further suggested increased soil matrix incorporation and retainment in relatively wetter soils (Shipitalo et al, 1990), and increased top-soil cracking allowing for increased downward flow of water and associated solutes during relatively drier periods of time (Brown et al, 1995) as plausible explanations. It could also be the case that increased run-off in relation to greater precipitation amounts could result in decreased groundwater contamination potential.…”
Section: Climate Parametersmentioning
confidence: 96%
“…Tiktak et al, 2004). However, on a more detailed note, it might be that dilution and run-off in relation to relatively larger amounts of precipitation, enhanced soil matrix incorporation and retainment in relatively wetter soils (Shipitalo et al, 1990), as well as increased top-soil cracking allowing for increased downward transport of water and associated solutes during relatively drier periods of time (Brown et al, 1995) need to be considered in terms of contamination potential.…”
Section: Overall Implications and Issuesmentioning
This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research and education use, including for instruction at the authors institution and sharing with colleagues.Other uses, including reproduction and distribution, or selling or licensing copies, or posting to personal, institutional or third party websites are prohibited. We have assessed the ability of a range of pesticide, site and climate parameters to discriminate between detected and non-detected pesticides as observed by long-term monitoring data of pesticide use and groundwater occurrence in a small catchment in southern Sweden. Of seventeen investigated parameters, six demonstrated such an ability: dosage applied, the Henry's Law Constant (HLC), the octanolwater partitioning coefficient (log P ow ), the amount of precipitation the week before application, the amount of precipitation the month after application, and the substance degradation potential (DT 50 ). The apparent influence of the investigated parameters on pesticide occurrence in groundwater, and their apparent suitability as descriptive parameters in terms of assessment of related risks, is accordingly discussed. We conclude that knowledge of actual pesticide use appear fundamental for risk assessment of groundwater contamination potential. We further suggest that chemical property-parameters of specific pesticides, although clearly valuable, should be applied in groundwater contamination risk assessments with care. If site-specific values are unattainable, tabular values of log P ow , HLC and water solubility (W s ) are demonstrated to exhibit a superior explanatory ability than those of substance adsorption potential (K oc ) and DT 50 which, in the latter case, is shown to be able to lead to misleading conclusions on actual risks.The demonstrated explanatory ability of precipitation both before and after application suggests that relatively greater precipitation amounts occur in relation to application of non-detected substances. Increased dilution and run-off as well as decreased soil matrix retainment and decreased top-soil cracking are potential explanations although higher-resolution monitoring records are needed in order to confirm these hypotheses.
“…-Whilst a prerequisite for estimation of overall contamination potential, in more detail, relatively more precipitation both before and after pesticide application may serve to decrease resultant groundwater concentrations and thus likelihood for detection. Dilution, increased run-off, decreased soil matrix retainment (Shipitalo et al, 1990) and decreased top-soil cracking (Brown et al, 1995) are potential explanations. More and higher-resolution studies of the effects of precipitation on pesticide contamination potential of groundwater in different environments and in relation to actual pesticide use are needed in order to be able to better and more accurately account for the resultant effects in terms of risk assessment of pesticide contamination of groundwater on different scales.…”
Section: Discussionmentioning
confidence: 99%
“…Other studies who have reported relatively less pesticide transport from wet than from dry soils have further suggested increased soil matrix incorporation and retainment in relatively wetter soils (Shipitalo et al, 1990), and increased top-soil cracking allowing for increased downward flow of water and associated solutes during relatively drier periods of time (Brown et al, 1995) as plausible explanations. It could also be the case that increased run-off in relation to greater precipitation amounts could result in decreased groundwater contamination potential.…”
Section: Climate Parametersmentioning
confidence: 96%
“…Tiktak et al, 2004). However, on a more detailed note, it might be that dilution and run-off in relation to relatively larger amounts of precipitation, enhanced soil matrix incorporation and retainment in relatively wetter soils (Shipitalo et al, 1990), as well as increased top-soil cracking allowing for increased downward transport of water and associated solutes during relatively drier periods of time (Brown et al, 1995) need to be considered in terms of contamination potential.…”
Section: Overall Implications and Issuesmentioning
This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research and education use, including for instruction at the authors institution and sharing with colleagues.Other uses, including reproduction and distribution, or selling or licensing copies, or posting to personal, institutional or third party websites are prohibited. We have assessed the ability of a range of pesticide, site and climate parameters to discriminate between detected and non-detected pesticides as observed by long-term monitoring data of pesticide use and groundwater occurrence in a small catchment in southern Sweden. Of seventeen investigated parameters, six demonstrated such an ability: dosage applied, the Henry's Law Constant (HLC), the octanolwater partitioning coefficient (log P ow ), the amount of precipitation the week before application, the amount of precipitation the month after application, and the substance degradation potential (DT 50 ). The apparent influence of the investigated parameters on pesticide occurrence in groundwater, and their apparent suitability as descriptive parameters in terms of assessment of related risks, is accordingly discussed. We conclude that knowledge of actual pesticide use appear fundamental for risk assessment of groundwater contamination potential. We further suggest that chemical property-parameters of specific pesticides, although clearly valuable, should be applied in groundwater contamination risk assessments with care. If site-specific values are unattainable, tabular values of log P ow , HLC and water solubility (W s ) are demonstrated to exhibit a superior explanatory ability than those of substance adsorption potential (K oc ) and DT 50 which, in the latter case, is shown to be able to lead to misleading conclusions on actual risks.The demonstrated explanatory ability of precipitation both before and after application suggests that relatively greater precipitation amounts occur in relation to application of non-detected substances. Increased dilution and run-off as well as decreased soil matrix retainment and decreased top-soil cracking are potential explanations although higher-resolution monitoring records are needed in order to confirm these hypotheses.
“…The opposite was observed when studying mobile herbicides' (isoproturon and mecocrop) transfer through a loamy clay soil (Brown et al, 1995a). In a soil column experiment, Shipitalo et al (1990) pointed out the effect on solute (bromide, strontium and atrazine) availability to transfer of slight precipitation occurring prior to heavy rainfall. Laboratory studies have also displayed the variability of pesticide movement depending on the humidity level of the soil (Geissbuhler et al, 1963;Green et al, 1968).…”
To cite this version:Sophie Guimont, Corinne Perrin-Ganier, Benoît Real, Michel Schiavon. Effects of soil moisture and treatment volume on bentazon mobility in soil. Abstract -Soil moisture affects the leaching behaviour of pesticides by inducing their physical entrapment in the soil structure. Columns containing soil aggregates were dampened to specific initial moisture levels. Bentazon was dripped onto surface aggregates in different volumes. The columns were then percolated after an equilibration period. Soil water from the columns was divided arbitrarily among mobile and immobile regions in order to describe the herbicide redistribution processes in the soil. When the soil was dry before treatment, bentazon losses by mass flow were 1.5 to 4 times higher than in wet conditions. Between application time and percolation, any water present in the porous matrix might favour pesticide diffusion towards immobile water regions as well as adsorption into and onto soil aggregates, preventing its leaching. The use of large solution volumes of the pesticide modifies surface soil moisture, suppressing any difference in behaviour between dry and wet soil application conditions. bentazon / diffusion / leaching / mobile water / immobile water
“…Esse uso intensivo, embora proporcione uma otimização econômica de uso do capital investido pelo produtor, acarreta algumas conseqüências que terminam por causar seqüelas ao meio ambiente, quais sejam: (i) maior quantidade de agro-químicos por hectare ano (ALBUS; KNIGHTON, 1998;NOLDIN et al, 2002), (ii) maior compactação de solo, pelo maior tráfego de máquinas e pelo impacto da gota de irrigação (AHUJA; LEHMAN, 1983;SHIPITALO et al, 1990) com conseqüente aumento no escorrimento superficial e do processo erosivo, (iii) maior incidência de pragas e doenças e seleção de populações de pragas resistentes aos pesticidas, o que aumenta a intensidade de uso dos mesmos, em um ciclo vicioso.…”
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