Initial-stage oriented-attachment one-dimensional assembly of nanocrystals: fundamental insight with a collision–recrystallization model

Abstract

Oriented attachment (OA) growth has been a promising method for the synthesis of one dimensional (1D) anisotropic nanocrystals (NCs). An unresolved fundamental issue is to understand the growth mechanism at the initial stage of an OA nanorod (NR) growth. In this report, a collision-recrystallization model is proposed to investigate the initial OA growth of NRs. The repulsive electrical double layer (EDL) interaction and the attractive van der Waals (vdW) interaction at the initial OA stage are derived by the accurate surface element integration (SEI) technique and the classical Hamaker equation, respectively. Our results show that the self-recrystallization of nanochains increases the collision activation energy of NPs dramatically as their surface potentials and Hamaker constants increase. Under a specific electrolyte concentration, the collision activation energy reaches the maximum, indicating that the growth rate of OA can be controlled by adjusting the electrolyte concentration.

Highly repeatable kinetically-independent synthesis of one- and two-dimensional silver nanostructures by oriented attachment

“…This would be in agreement with published papers, in which the alignment and assembly of their particles was inuenced by coulombic interaction between the particles and effect of solvation forces in a collision-recrystallization growth process. [29][30][31] These mechanisms were inuenced by the geometry of their particles, and the local charges associated with them, generally agreeing with the pH sensitivity reported here. However, those studies were modelled with highly-idealized radially symmetric particle geometries representing simplied cases, and so more work would be necessary to verify this is applicable to the nano-structures studied here.…”

“…The orientation and assembly of nanoparticles during nonclassical crystallization is a challenging subject which is not well understood, and is a rapidly developing eld. [29][30][31] However, more investigation seems to be required to clarify all affecting parameters.…”