1986
DOI: 10.1002/polb.1986.090241101
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Initial relaxation times in dynamic light scattering from once‐broken rod molecules in solution

Abstract: Initial relaxation times determined by the initial decay rate of the time correlation function of scattered light are calculated for the once‐broken rod model (two rigid rods of equal length connected by a universal joint) following the Fujiwara–Saito theory. The coefficient C describing the initial angular dependence of the first cumulant of the correlation function is also calculated. The results are compared with Pecora's results based on the Yu–Stockmayer theory for this model; and it is shown that the Fuj… Show more

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“…Other properties of broken rods, such as dynamic light scattering Moro and Fujiwara 1986) and rheological behavior (Jorquera et al 1990), have been calculated theoretically. It is hoped that Brownian Dynamics will be soon extended to these properties, in order to verify the theoretical predictions.…”
Section: The Broken Rodmentioning
confidence: 99%
“…Other properties of broken rods, such as dynamic light scattering Moro and Fujiwara 1986) and rheological behavior (Jorquera et al 1990), have been calculated theoretically. It is hoped that Brownian Dynamics will be soon extended to these properties, in order to verify the theoretical predictions.…”
Section: The Broken Rodmentioning
confidence: 99%