Inhibition effect of nicotinamide and its Mannich base derivatives on mild steel corrosion in HCl

Jeeva, Mani; Prabhu, G. Venkatesa; Rajesh, Chinnaiyan Mahalingam

doi:10.1007/s10853-017-1401-2

Cited by 23 publications

(13 citation statements)

References 61 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…In our case, the low value of 4.1582 eV when compared with that of many good inhibitors in the literature could explain the good inhibition efficiency of TBNBI (Jeeva et al, 2017).…”

Section: Global Parametersmentioning

confidence: 46%

See 1 more Smart Citation

Corrosion Inhibition of Copper in 2M Nitric Acid Solution by 2-(Thiobenzyl)-5-Nitro-1H-Benzimidazole

Coulibaly

Brou

Akpa

et al. 2018

IJAPSR

View full text Add to dashboard Cite

Pickling with nitric acid is commonly practiced in industry for finishing metal surfaces. The use of inhibitors during the pickling operation is of very recent origin. The TBNBI inhibition effect on copper corrosion in 2M nitric acid solution was investigated by weight loss method in relation to the temperature (25 to 40°C) and inhibitor concentration range 10-4 to 5.10-3 M. The results show that TBNBI is a good inhibitor for copper and the inhibition efficiency increases with concentration of TBNBI but decreases with increase in temperature. The adsorption parameters 0 00(G H Sads ads a, ,)ds∆∆∆ and the activation ones **a aa(E,H,S)∆∆ for the corrosion process in inhibited and uninhibited nitric acid solution were also calculated using Arrhenius equations. It can be con-cluded that the adsorption of the compound is spontaneous and found to occur through both physisorption and chemisorption processes. The adsorbed film on copper surface was characterized using optic microscopy and Raman spectroscopy. The surface analysis confirmed the inhibition action of TBNBI. Quantum chemical calculations using Gaussian 09 at B3LYP level with 6-31G (d,p) basis set lead to obtain molecular descriptors such as EHOMO (energy of the highest occupied molecular orbital), ELUMO (energy of the lowest unoccupied molecular orbital), ∆E (energy gap) and μ (dipole moment). The global reactivity descrip-tors such asχ (electronegativity), η (hardness), S (softness) and ω (electrophilicity index) were derived using Koopman’s theorem and analyzed. We used the condensed Fukui function and softness indices, Mulliken population analysis for local reactivity study. The calculated results are consistent with the experimental data.

show abstract

“…In our case, the low value of 4.1582 eV when compared with that of many good inhibitors in the literature could explain the good inhibition efficiency of TBNBI (Jeeva et al, 2017).…”

Section: Global Parametersmentioning

confidence: 46%

“…In this method the chemical reactivity of inhibitors can be evaluated for each atom. The nucleophilic ( ( ) Fukui functions can be calculated using the finite difference approximation as follows(Jeeva et al, 2017):…”

mentioning

confidence: 99%

Corrosion Inhibition of Copper in 2M Nitric Acid Solution by 2-(Thiobenzyl)-5-Nitro-1H-Benzimidazole

Coulibaly

Brou

Akpa

et al. 2018

IJAPSR

View full text Add to dashboard Cite

show abstract

“…Steel and its alloys to be used worldwide in the field of microelectronic because of its excellent mechanical performances, cost‐effectiveness, and facile fabrication 1 . However, steel oxidize and corrosion easily occur due to corrosion in metal‐forming process, which owing to the aggressive chloride ions in aqueous and emulsion 2,3 . By addressing this problem, a lot of measures have been taken to improve the anticorrosion properties of mild steel, and the addition of corrosion inhibitors is one of the best ways to inhibit corrosion 4–6 .…”

Section: Introductionmentioning

confidence: 99%

“…1 However, steel oxidize and corrosion easily occur due to corrosion in metal-forming process, which owing to the aggressive chloride ions in aqueous and emulsion. 2,3 By addressing this problem, a lot of measures have been taken to improve the anticorrosion properties of mild steel, and the addition of corrosion inhibitors is one of the best ways to inhibit corrosion. [4][5][6] Therefore, all kinds of chemicals containing several heteroatoms (i.e., N, S, and O) have already been used as the inhibitors to hinder the corrosion of mild steel in the past several decades.…”

Section: Introductionmentioning

confidence: 99%

Study on corrosion behavior of new corrosion inhibitor imidazole derivatives for mild steel in oil‐in‐water emulsion

Xiong

Liu

et al. 2020

Surface & Interface Analysis

View full text Add to dashboard Cite

Two imidazole derivatives, 2‐(2‐((benzo[d]thiazol‐2‐ylthio)methyl)‐4,5‐dihydro‐1H‐imidazol‐1‐yl)ethan‐1‐ol (BTM) and 2‐(2‐((1H‐benzo[d][1,2,3]triazol‐1‐yl)methyl)‐4,5‐dihydro‐1H‐imidazol‐1‐yl)ethan‐1‐ol (BTMS), as a new corrosion inhibitor were synthesized, and their inhibition behaviors for mild steel contained in emulsion were investigated by gravimetric experiment, electrochemical tests, and theoretical calculations. The results show that the inhibition effect of BTMS is better than that of BTM, the maximum value of the inhibition efficiency reaches 97.9%. The resultant adsorption films from BTM/BTMS adsorbed on mild steel, effectively inhibiting the corrosion of mild steel is mainly through chemisorption and follow to Langmuir's adsorption isotherm.

show abstract

“…Mannich bases are considered being good corrosion inhibitors, the presence of heteroatom (O, N & S) and conjugated double bonds are reason for their corrosion inhibition properties. [6] Recently, urea, [7] thiourea, [6b] indole, [8] isatin, [9] nicotinamide, [10] melamine [11] derived Mannich bases have been reported as corrosion inhibitors. Most of the reported Mannich base inhibitors follow adsorption mechanism.…”

Section: Introductionmentioning

confidence: 99%

Adsorption Effect of Five‐Membered and Six‐Membered Alicyclic Amine‐Derived Mannich Bases on Mild Steel Surface in 1.0 M HCl

Nesaian

Prabhu

2017

ChemistrySelect

View full text Add to dashboard Cite

Two new Mannich bases N‐(3‐(benzo[d][1, 3]dioxol‐5‐yl(pyrrolidin‐1‐yl)methyl)‐4‐hydroxyphenyl)acetamide (I1) and N‐(3‐(benzo[d][1, 3]dioxol‐5‐yl(morpholino)methyl)‐4‐hydroxyphenyl) acetamide (I2) are synthesised and evaluated their corrosion inhibition behaviour through weight loss measurements, electrochemical, quantum chemical and surface analytical studies. Tafel studies revealed that the inhibitors are found to be mixed type. EIS studies confirmed that corrosion process is controlled through charge transfer process. The adsorption of inhibitors I1 and I2 follows Langmuir adsorption isotherm and ΔGads values suggest that both physorption and chemisorption are possible. Surface studies show that in the presence of inhibitors, smoother surface is obtained compared to blank. I1 has higher inhibition efficiency (50 μM −98%) than I2 (50 μM −94%) which is correlated with the theoretical studies.

show abstract

Inhibition effect of nicotinamide and its Mannich base derivatives on mild steel corrosion in HCl

Cited by 23 publications

References 61 publications

Corrosion Inhibition of Copper in 2M Nitric Acid Solution by 2-(Thiobenzyl)-5-Nitro-1H-Benzimidazole

Corrosion Inhibition of Copper in 2M Nitric Acid Solution by 2-(Thiobenzyl)-5-Nitro-1H-Benzimidazole

Study on corrosion behavior of new corrosion inhibitor imidazole derivatives for mild steel in oil‐in‐water emulsion

Adsorption Effect of Five‐Membered and Six‐Membered Alicyclic Amine‐Derived Mannich Bases on Mild Steel Surface in 1.0 M HCl

Contact Info

Product

Resources

About