Infrared spectra of C- and B-hydroxycarboranes(12) and peculiarities of the electronic structure of these compounds

Klimova, T. P.; Brattsev, V. A.; Anorova, G. A.; Gol’tyapin, Yu. V.; Stanko, V. I.

doi:10.1007/bf00604432

Search citation statements

Order By: Relevance

Paper Sections

Select...

Methods1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1980

2003

Publication Types

Select...

Article1

Book1

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

(1 citation statement)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Compound 12 (139 mg, 0.869 mmol) could be isolated as a white solid by subsequent eluation with a 1:4 mixture of diethyl ether and pentane. The analytical data of 12 were consistent with those reported in the literature (mp, MS, and elementary analysis). , NMR data of 12 have not been reported previously and are given here. 1 H NMR MHz (CDCl 3 ): δ 3.12 (s, 1H, HC-cage), 2.70 (s, 1H, HC-cage) and 2.50 (s, 1H, OH).…”

Section: Methodssupporting

confidence: 90%

Palladium-Catalyzed Heck Reactions of Styrene Derivatives and 2-Iodo-p-carborane

et al. 2003

View full text Add to dashboard Cite

p-Carborane has been vinylated on the 2-B-atom in high yields using the Heck reaction. Thus, the reaction between 2-iodo-p-carborane and various styrenes [4-H-, 4-C(6)H(4)-, 4-Cl-, 4-Br-, 4-NO(2)-, 4-CH(3)O-, and 4-CH(3)-] resulted in the production of the corresponding trans-beta-(2-B-p-carboranyl)styrene in DMF solution when reacted in the presence of silver phosphate and the palladacycle Herrmann's catalyst.

show abstract

Section: Methodssupporting

confidence: 90%