Infrared photodissociation spectroscopy of heteronuclear group 15 metal–iron carbonyl cluster anions AmFe(CO)n− (A = Sb, Bi; m, n = 2, 3)

Meng, Luyan; Liu, Siying; Qin, Qifeng; Zeng, Bin; Luo, Zhen; Chi, Chaoxian

doi:10.1039/d1cp00583a

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2023

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“…Recently, many hetero-dinuclear metal carbonyl cluster anions and cations have been produced in the gas phase and spectroscopically examined. 26–51 The FeM(CO) 8 + (M = Co, Ni, Cu) clusters were characterized to possess the (CO) 5 Fe–M(CO) 3 structures, and could be viewed as being formed via the interaction of a neutral Fe(CO) 5 fragment with an M(CO) 3 + fragment. 26 The square pyramid Fe(CO) 5 neutral with an 18-electron configuration acted as a two-electron donor in forming an σ-type Fe → M dative single bond.…”

Section: Introductionmentioning

confidence: 99%