1969
DOI: 10.21236/ad0700126
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Infrared Determination of Inorganic Sulfates and Carbonates by the Pellet Technique

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Cited by 5 publications
(8 citation statements)
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“…The bands at 2370 cm −1 , 1610 cm −1 , 1425 cm −1 , 1058 cm −1 (shoulder), 1030 cm −1 , 885 cm −1 , and 680 cm −1 of the contaminated PSC were almost identical to those at 2450 cm −1 , 1750 cm −1 , 1625 cm −1 (weak band), 1425 cm −1 , 1050 cm −1 , 850 cm −1 , and 690 cm −1 of the reagent grade barium carbonate in the literature [24], taking into account the variation of different IR instruments and samples in use. The IR bands of the PSCs and literature barium carbonate are given in Table 6.…”
Section: Effect Of Contaminated Soil On Psc Characteristicssupporting
confidence: 71%
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“…The bands at 2370 cm −1 , 1610 cm −1 , 1425 cm −1 , 1058 cm −1 (shoulder), 1030 cm −1 , 885 cm −1 , and 680 cm −1 of the contaminated PSC were almost identical to those at 2450 cm −1 , 1750 cm −1 , 1625 cm −1 (weak band), 1425 cm −1 , 1050 cm −1 , 850 cm −1 , and 690 cm −1 of the reagent grade barium carbonate in the literature [24], taking into account the variation of different IR instruments and samples in use. The IR bands of the PSCs and literature barium carbonate are given in Table 6.…”
Section: Effect Of Contaminated Soil On Psc Characteristicssupporting
confidence: 71%
“…IR absorption bands (cm −1 ) of the original PSC, radiocontaminated PSC, and literature barium carbonate[24].…”
mentioning
confidence: 99%
“…Figure shows the spectra of a K 2 CO 3 sample subjected to different relative humidity conditions at 40 °C under a flush of N 2 . It is noticed that the sample dried in air at 160 °C presented only the peaks corresponding to the anhydrous carbonate ion, CO 3 –2 : out-of-plane bending at 879 cm –1 , asymmetric stretching at 1400 cm –1 , and in-plane bending at 686 cm –1 . When the salt was subjected to increasing humidity conditions, the spectrum changed significantly.…”
Section: Results Of the Hydration Experimentsmentioning
confidence: 99%
“…It is noticed that the sample dried in air at 160 °C presented only the peaks corresponding to the anhydrous carbonate ion, CO 3 −2 : out-of-plane bending at 879 cm −1 , asymmetric stretching at 1400 cm −1 , and in-plane bending at 686 cm −1 . 48 When the salt was subjected to increasing humidity conditions, the spectrum changed significantly. At 7% RH the initial peaks corresponding to the anhydrous carbonate were still present, although the strongest peak at 1400 cm −1 was now a shoulder and new peaks appeared at 1449, 1350, 1060, and 704 cm −1 .…”
Section: Results Of the Hydration Experimentsmentioning
confidence: 99%
“…34 These observations suggested similar structures for both nitric and sulfuric systems, but also a possible absence of participation of the counter-ion in the coordination sphere of Pu in the solution or in the precipitate. Fourier Transform Infra-Red (FT-IR) spectroscopy on the solids obtained in both nitric and sulfuric media showed the characteristic signatures of nitrates, 29,35 sulphates 34,36 and interstitial and/or coordinated water molecules (Fig. S4, ESI †).…”
mentioning
confidence: 99%