Abstract:Multiple scattering effects influence the transport properties of excess electrons in gaseous and fluid dielectrics but also affect the energy levels of electrons in delocalized molecular orbitals and can be investigated by carrying out spectroscopic observations. We have measured the infrared cathodoluminescence of the Xe2 excimer in dense Xe gas, and in Xe-He, and Xe-N2 mixtures. The large orbital characterizing the weakly bound, optically active electron of Xe2 encompasses several surrounding atoms and allo… Show more
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