2018
DOI: 10.21577/0100-4042.20170280
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Influência Da Rigidez Do Meio Na Cinética Do Fotocromismo De Ditizonatos Metálicos

Abstract: INFLUENCE OF THE MEDIUM RIGIDITY ON THE PHOTOCHROMISM KINETICS OF METAL DITHIZONATES. The kinetics of photoisomerization and thermal back reaction of mercury(II) and zinc(II) dithizonates, M(HDz) 2 , were analyzed by photolysis assays in fluid solution and in poly(methyl methacrylate), PMMA, films. In fluid solution, the photo-and thermoisomerization of both complexes can be described by a single exponential function. The Zn(II) dithizonate exhibits rate constants three orders of magnitude greater than that fo… Show more

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