Three
different ranks of Chinese coals were investigated on the
thermal conductivity and corresponding molecular structure by thermal
analyzer,
13
C NMR, and HRTEM techniques. The thermal conductivity
of coals measured in room temperature first shows a decrease, then
a slight increase, and finally a sharp increase with increasing coalification.
Ranging from 30 to 150 °C, increasing the temperature slightly
improves the thermal conductivity of coals with varying degrees. Water
with a higher thermal conductivity than air contributes to the thermal
conductivity of porous coal samples. The value of thermal conductivity
is higher along coal bedding planes than when perpendicular to beddings,
which indicates the anisotropy of coal thermal conductivity. The anisotropy
degree increases with the rank of coals and is affected by clay minerals
when coals adsorb water. Molecular structure analysis shows that polycondensed
aromatic ring related to lattice vibration contributes to the increase
of thermal conductivity. The aliphatic bridges among aromatic clusters
ensure the continuity of atom vibrations and contribute to energy
transport, but the free-ended side chains have the opposite effect.
The relative ordered distributions of lattice fringes of anthracite,
which were higher than those of bituminous coal, enhance the anisotropy
of thermal conductivity.