Influence of ZnO doping and calcination temperature of nanosized CuO/MgO system on the dehydrogenation reactions of methanol

Abstract

Pure and doped catalysts were prepared with ZnO dopant concentration (0.04-0.08 mol) by wet impregnation method followed by calcination at 350-650°C. The prepared solids were characterized by X-ray diffraction, N 2 -adsorption at -196°C and the methanol conversion as the catalytic probe reaction. The results revealed that the crystallite size and ordering of CuO phase decrease by ZnO-doping for samples calcined at 350-550°C. Opposite trends were observed by increasing ZnO amount to 0.08 mol (i.e. 9.21 wt%). The specific surface area (S BET ) and the catalytic activity of pure catalyst increase by increasing the calcination temperature to 550°C and/or increasing the amounts of ZnO up to certain extent reaching to a maximum at 7.07 wt% ZnO; above this concentration catalytic activity of doped samples decreases. But at calcination temperature above 550°C, the catalytic activity and selectivity decrease. The prepared catalysts are selective towards formaldehyde and methyl formate formation.