Influence of Various Precursor Compositions and Substrate Angles on ZnO Nanorod Morphology Growth by Aqueous Solution Method

Abstract

Abstract. ZnO nanorods were synthesized on silicon wafer substrate with a seed zinc layer using the aqueous solution method. The influence of various precursor compositions on the morphology of the ZnO nanorods, with substrate angles at 0 and 90, was investigated. The various ratios of hexamethylenetetramine in zinc nitrate hexahydrate were used as precursors in the synthesis of ZnO. Scanning electron micrography indicated that the growth of the ZnO nanorods with a 0 substrate angle was smaller than with a 90 substrate angle. The substrate angle is defined as the angle between the plane of the substrate and the horizontal layer of an aqueous solution. When the precursor concentration of hexamethylenetetramine is not equal to the ratio corresponding to the chemical reaction, the effect of the substrate angle on the diameter size and morphology of the ZnO nanorods is evident. Grazing incident X-ray diffraction (GIXRD) was used to characterize the structure of all samples. The diffraction patterns showed that the orientation matched the hexagonal wurtzite structure.

Controlled Growth of Semiconducting ZnO Nanorods for Piezoelectric Energy Harvesting-Based Nanogenerators

“…Puenisara et al [ 162 ] use the aqueous solution method to investigate the effect of precursor concentrations and substrate angles on ZnO-NR morphology growth. ZnO nanorods were synthesized on a silicon substrate with a seed zinc layer, and the morphology of the nanorods was studied at substrate angles of 0° and 90°.…”