Abstract:Zr-C thin films are grown on single-crystalline MgO(001) substrates via ultra-high vacuum dc magnetron sputtering of Zr target in 10 mTorr Ar-C2H4 gas mixtures with ethylene partial pressures (p C 2 H 4) between 2 × 10-7 Torr and 2 × 10-4 Torr at substrate temperature Ts = 923 K and using p C 2 H 4 = 2 × 10-6 Torr at 723 K ≤ Ts ≤ 1123 K. The as-deposited layer microstructure and composition are determined using X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. We find t… Show more
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