“…So far, a series of rare earth doped oxyfluoride glass-ceramics have been obtained since it was reported by Wang and Ohwaki [5][6][7], in which the spectroscopic properties of the glass ceramics were greatly enhanced. In recent years, most of the research work in fluoride glass ceramics has focused on their application as X-ray storage phosphors [8][9][10], while only a few studies on the spectroscopic properties of rare earth ions in fluoride glass ceramics were reported [11,12]. In the present work, we describe the preparation and the spectroscopic properties of Er 3+ in new multicomponent ZrF 4 -ZnF 2 -AlF 3 -YF 3 -MF 2 (M = Ca Sr Ba) based glass ceramics.…”