The paper describes the influence of thermomagnetic treatment on the parameters of the amplitude dependence of internal friction, the crystal and magneto-crystalline structure of Fe alloys with ferrite structure: Fe – 8%Cr, Fe – 16%Cr, Fe – 19%Cr, Fe – 4%Cr – 2%V, Fe – 3%Cr – 3%Al, and Fe–1.2%C–2% Si–2%Al graphitic steel with graphite and ferrite structure. The thermomagnetic treatment was carried out at a temperature of 450ºС. The structure was studied by means of metallography, X-ray crystal structure analysis, ferromagnetic resonance, and nuclear gamma resonance spectroscopy. It is shown that, the larger the ferrite grain in alloys with ferrite structure is, the greater an increase in internal friction is, in the amplitude range up to approximately the amplitude of its maximum owing to thermomagnetic treatment. The change of the damping properties of graphitic steel caused by thermomagnetic treatment is relatively small, due to a large number of diamagnetic inclusions of graphite and quite fine-grained ferrite matrix. The results of the X-ray crystal structure analysis, the ferromagnetic resonance and nuclear gamma resonance spectroscopy have shown that, in the case of thermomagnetic treatment, diffusion redistribution of atoms of alloying elements, combined with the change of structural anisotropy, takes place in Fe-Cr alloys.